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Chemical Foundations of Biological Systems: Elements, Atoms, and the Periodic Table

Study Guide - Smart Notes

Tailored notes based on your materials, expanded with key definitions, examples, and context.

Chapter 2: Chemical Foundations of Biological Systems

Concept 2.1: Matter, Elements, and Compounds

Matter is anything that occupies space and has mass. All living organisms are composed of matter, which exists in the form of elements and compounds. Elements are pure substances that cannot be broken down by ordinary chemical reactions, while compounds are substances formed from two or more elements in fixed ratios.

  • Element: A substance consisting of only one type of atom, with unique chemical properties.

  • Compound: A substance formed when two or more elements combine chemically in a fixed ratio.

  • Mixture: A physical combination of two or more substances where each retains its own properties.

Diagram showing elements as single atoms and diatomic moleculesDiagram showing mixtures of different elements and molecules

Essential elements are required for life, with oxygen (O), carbon (C), hydrogen (H), and nitrogen (N) making up the majority of living matter. Mineral elements and trace elements are required in smaller quantities but are crucial for regulatory, structural, and metabolic functions.

Mineral Elements (less than 1% of total mass)

Symbol

Calcium

Ca

Chlorine

Cl

Magnesium

Mg

Phosphorus

P

Potassium

K

Sodium

Na

Sulfur

S

Table of mineral elements

Trace Elements (less than 0.01% of total mass)

Symbol

Chromium

Cr

Cobalt

Co

Copper

Cu

Fluorine

F

Iodine

I

Iron

Fe

Manganese

Mn

Molybdenum

Mo

Selenium

Se

Silicon

Si

Tin

Sn

Vanadium

V

Zinc

Zn

Table of trace elements

The Periodic Table of Elements

The periodic table organizes all known elements based on their atomic number, electron configuration, and recurring chemical properties. It is a fundamental tool for understanding chemical behavior in biological systems.

  • Groups (columns): Elements with similar chemical properties and the same number of valence electrons.

  • Periods (rows): Elements with the same number of electron shells.

Periodic table of the elements

Concept 2.2: Atomic Structure and Properties

Atomic Structure

An atom is the smallest unit of an element that retains its chemical properties. Atoms are composed of three types of subatomic particles: protons, neutrons, and electrons. The nucleus contains protons and neutrons, while electrons occupy orbitals around the nucleus.

  • Proton: Positive charge, mass of 1 amu, located in the nucleus.

  • Neutron: No charge, mass of 1 amu, located in the nucleus.

  • Electron: Negative charge, negligible mass, located in orbitals.

Diagram of atomic structure showing nucleus and electron cloudHydrogen and Helium atomic structure

Particle

Charge

Mass (amu)

Location

Proton

+1

1

Nucleus

Neutron

0

1

Nucleus

Electron

-1

0

Orbitals

Table of protons, neutrons, and electronsDiagram showing charges and masses of subatomic particles

Atomic Number, Mass Number, and Isotopes

The atomic number is the number of protons in an atom and defines the element. The mass number is the sum of protons and neutrons. Isotopes are atoms of the same element with different numbers of neutrons. Some isotopes are radioactive and have important applications in biology and medicine.

  • Atomic number (Z): Number of protons in the nucleus.

  • Mass number (A): Number of protons plus neutrons.

  • Isotope: Atoms of the same element with different neutron numbers.

  • Radioactive isotope: Unstable isotope that decays, emitting radiation.

Periodic table entry for hydrogenCalculation of mass number, atomic number, and neutronsStable and unstable carbon isotopesPET scan showing cancerous tissue

Example: Carbon-12, Carbon-13, and Carbon-14 are isotopes of carbon. Carbon-14 is radioactive and used in radiometric dating.

Atomic Structure of Beryllium

Beryllium (Be) has an atomic number of 4 and a mass number of approximately 9. Its nuclear notation is , indicating 4 protons and 5 neutrons.

Beryllium atom structureBeryllium atom structurePeriodic table entry for BerylliumBeryllium atom structure

Electron Arrangement and Reactivity

The arrangement of electrons in shells (energy levels) determines an element's chemical reactivity. Electrons fill shells from the lowest to highest energy, and the outermost shell is called the valence shell. Atoms are most stable when their valence shell is full, typically with 8 electrons (the Octet Rule).

  • Bohr Model: Electrons orbit the nucleus in discrete energy levels (shells).

  • Valence electrons: Electrons in the outermost shell, important for chemical bonding.

  • Octet Rule: Atoms tend to gain, lose, or share electrons to achieve 8 electrons in their valence shell (except for hydrogen and helium).

Hydrogen atom electron shellChlorine atom electron shellNeon atom electron shellElectron energy levels and transitionsOctet rule diagram

The Periodic Table and Electron Configuration

The periodic table provides information about the number of electron shells, valence electrons, and types of orbitals (s, p, d, f) for each element. Electron configuration determines chemical properties and bonding behavior.

  • Groups: Indicate the number of valence electrons.

  • Periods: Indicate the number of electron shells.

  • Blocks (s, p, d, f): Indicate the type of orbital being filled.

Periodic table with electron shells and valence electronsPeriodic table with s, p, d, f blockss and p orbitals and hybridizationNitrogen atom showing electrons in orbitalsNitrogen atom showing electrons in shells

Chemical Bonding and Reactivity

Atoms with incomplete valence shells are chemically reactive and can form bonds to achieve stability. Atoms with full valence shells are chemically inert (noble gases).

  • Covalent bond: Sharing of electron pairs between atoms.

  • Ionic bond: Transfer of electrons from one atom to another, resulting in oppositely charged ions.

  • Example: Hydrogen and chlorine can bond because they have incomplete valence shells, while neon cannot bond because its valence shell is full.

Electron shell diagrams showing bonding abilityElectron shell diagrams showing bonding abilityElectron shell diagrams showing bonding abilityElectron shell diagrams showing bonding ability

Summary Table: Electron Shells and Reactivity

Element

Valence Electrons

Reactivity

Hydrogen (H)

1

Reactive

Chlorine (Cl)

7

Reactive

Neon (Ne)

8

Inert

Electron shell diagrams for various elements

Additional info: Understanding atomic structure and the periodic table is foundational for studying biological molecules, cellular processes, and metabolism in living systems.

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