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Terms in this set (15)
What components make up a buffer solution?
A buffer solution contains a weak acid and its conjugate base, or a weak base and its conjugate acid.
Why do buffer solutions resist drastic changes in pH?
Buffers resist pH changes by neutralizing added strong acids or bases, keeping H+ and OH- concentrations nearly constant.
What happens when a small amount of strong base is added to a buffer?
The weak acid in the buffer neutralizes the strong base, causing only a slight increase in pH.
What happens when a small amount of strong acid is added to a buffer?
The conjugate base in the buffer neutralizes the strong acid, causing only a slight decrease in pH.
What destroys a buffer solution?
Adding too much strong acid or strong base destroys a buffer; adding water does not affect it.
Why does adding water not destroy a buffer?
Adding water changes the concentrations of both the weak acid and conjugate base proportionally, so their ratio remains the same.
What is the ideal ratio of weak acid to conjugate base in a buffer?
The ideal buffer has equal amounts of weak acid and conjugate base, typically at the half equivalence point.
What is the buffer range for a good buffer?
A good buffer has a weak acid to conjugate base ratio between 10:1 and 1:10.
What is buffer capacity?
Buffer capacity refers to how well a buffer can neutralize added acid or base; higher concentrations of buffer components increase capacity.
What are the three ways to make a buffer?
Buffers can be made by mixing a weak acid with its conjugate base, a weak base with a strong acid (weak base in excess), or a weak acid with a strong base (weak acid in excess).
What must be true when making a buffer from a weak base and strong acid?
The weak base must be present in a higher amount than the strong acid; otherwise, the buffer will be destroyed.
What must be true when making a buffer from a weak acid and strong base?
The weak acid must be present in a higher amount than the strong base; otherwise, the buffer will be destroyed.
What equation is used to calculate the pH of a buffer?
The Henderson-Hasselbalch equation is used: pH = pKa + log([conjugate base]/[weak acid]).
What does 'pKa' represent in the Henderson-Hasselbalch equation?
pKa is the negative logarithm of the acid dissociation constant (Ka) for the weak acid.
Can you use moles or molarity in the Henderson-Hasselbalch equation?
Yes, you can use either moles or molarity for the conjugate base and weak acid, depending on the information given.