Classification of Ligands definitions Flashcards
Classification of Ligands definitions
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LigandsLewis bases that donate lone pairs to metal cations, classified by the number of donor atoms.MonodentateLigands with one donor atom that can donate a lone pair to a central metal.BidentateLigands with two donor atoms, separated by at least two other atoms, that can donate lone pairs.PolydentateLigands with more than two donor atoms, capable of forming multiple bonds with metal cations.ChelatesStable ring structures formed when polydentate ligands bond to metal cations.Donor atomsAtoms in a ligand that donate lone pairs to a central metal, often negatively charged.HydroxideA common monodentate ligand with a negatively charged oxygen as the donor atom.AmmoniaA monodentate ligand where nitrogen donates a lone pair to a central metal.CyanideA monodentate ligand with a negatively charged carbon as the donor atom.EthylenediamineA bidentate ligand with two nitrogen donor atoms separated by two carbon atoms.EDTAA well-known polydentate ligand with six donor atoms, used as a preservative.Chelating agentsBidentate and polydentate ligands that form stable ring structures with metals.Complex ionA structure formed when ligands bond to a central metal, often more stable with chelating agents.Ring structuresFormed by chelating agents in complex ions, ideally 5 or 6 membered for stability.OxalateA bidentate ligand with two negatively charged oxygen donor atoms.