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Chapter 4: Molecular Compounds – Study Notes

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Chapter 4: Molecular Compounds

4.1 Covalent Bonds

Covalent bonds are a fundamental type of chemical bond where two atoms share one or more pairs of electrons. This sharing allows each atom to achieve a stable electron configuration, often resembling that of the nearest noble gas.

  • Covalent Bond: A bond formed by the sharing of electrons between two nonmetal atoms.

  • Molecule: A group of atoms held together by covalent bonds, forming a distinct entity.

  • Main group elements tend to react to achieve eight valence electrons (the octet rule), except hydrogen, which achieves two.

  • Nonmetals achieve an octet by sharing electrons in covalent bonds.

Example: The hydrogen molecule (H2) forms when two hydrogen atoms share their 1s electrons, resulting in a stable electron pair between them. This can be represented as H–H, H:H, or H2.

Covalent bonding in hydrogen: 1s electrons from two hydrogen atoms overlap to form a shared electron pair in a hydrogen molecule

  • Bond Length: The optimal distance between the nuclei of two bonded atoms, where attractive and repulsive forces are balanced.

  • Other diatomic elements (e.g., N2, O2, F2, Cl2, Br2, I2) also form by sharing electrons.

Additional info: Covalent bonds differ from ionic bonds, where electrons are transferred rather than shared. Covalent bonds typically occur between nonmetals, while ionic bonds form between metals and nonmetals.

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