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Combustion of Ethanol: Equation Balancing and Stoichiometric Calculations

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Combustion Reactions and Stoichiometry

Combustion of Ethanol

The combustion of ethanol (C2H5OH) is a chemical reaction in which ethanol reacts with oxygen to produce carbon dioxide and water. This is an example of a complete combustion reaction, which is important in both energy production and biochemical processes.

  • Combustion Reaction: A reaction where a substance reacts with oxygen gas, releasing energy, carbon dioxide, and water.

  • Ethanol: A simple alcohol with the formula C2H5OH.

Balanced Chemical Equation

To write and balance the combustion equation for ethanol:

  • General form: Alcohol + O2 → CO2 + H2O

The unbalanced equation:

C2H5OH + O2 → CO2 + H2O

Balancing the equation:

  • Count atoms of each element on both sides.

  • Balance C, then H, then O.

Balanced equation:

Stoichiometric Calculation: Mass of CO2 Produced

To find the mass of CO2 produced when 10.0 g of ethanol burns completely:

  1. Calculate moles of ethanol:

    • Molar mass of C2H5OH = (2 × 12.01) + (6 × 1.01) + 16.00 = 46.08 g/mol

    • Moles of ethanol =

  2. Use the balanced equation to find moles of CO2:

    • From the equation: 1 mol ethanol produces 2 mol CO2

    • Moles of CO2 =

  3. Calculate mass of CO2 produced:

    • Molar mass of CO2 = 12.01 + (2 × 16.00) = 44.01 g/mol

    • Mass of CO2 =

Summary Table: Stoichiometric Relationships

Substance

Moles Used/Produced

Molar Mass (g/mol)

Mass (g)

Ethanol (C2H5OH)

0.217

46.08

10.0

CO2

0.434

44.01

19.1

Key Points

  • Combustion reactions are a major source of energy and are important in metabolism and industry.

  • Balancing chemical equations ensures the law of conservation of mass is obeyed.

  • Stoichiometry allows calculation of product amounts from given reactant quantities.

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