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Ch.12 - Solids and Modern Materials
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232Non è quello che usi tu?Cambia libro di testo
Capitolo 12, Problema 101

Which statement correctly describes a difference between graphene and graphite? (a) Graphene is a molecule but graphite is not. (b) Graphene is a single sheet of carbon atoms and graphite contains many, and larger, sheets of carbon atoms. (c) Graphene is an insulator but graphite is a metal. (d) Graphite is pure carbon but graphene is not. (e) The carbons are sp2 hybridized in graphene but sp3 hybridized in graphite.

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Understand the structure of graphene: Graphene is a single layer of carbon atoms arranged in a two-dimensional honeycomb lattice.
Understand the structure of graphite: Graphite consists of many layers of graphene stacked on top of each other, with weak van der Waals forces between the layers.
Compare the structures: Graphene is a single sheet, while graphite is composed of multiple sheets of graphene.
Consider the hybridization: Both graphene and graphite have carbon atoms that are sp2 hybridized, not sp3.
Evaluate the options: Option (b) correctly describes the difference between graphene and graphite, as graphene is a single sheet and graphite contains many sheets.

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Structure of Graphene and Graphite

Graphene is a single layer of carbon atoms arranged in a two-dimensional honeycomb lattice, while graphite consists of multiple layers of graphene stacked together. This structural difference leads to distinct physical properties, such as electrical conductivity and mechanical strength, making graphene a highly sought-after material in various applications.
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Resonance Structures

Hybridization of Carbon Atoms

In graphene, each carbon atom is sp2 hybridized, meaning it forms three sigma bonds with neighboring carbon atoms and has one unhybridized p orbital that contributes to delocalized pi bonding. In contrast, graphite's carbon atoms are also primarily sp2 hybridized, allowing for similar bonding characteristics, but the presence of multiple layers affects the overall properties of the material.
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Electrical Conductivity

Graphene is an excellent conductor of electricity due to its structure, which allows for the free movement of electrons across its surface. Graphite, while also a good conductor, exhibits different conductivity characteristics because of its layered structure, which can impede electron flow between layers. Understanding these differences is crucial for applications in electronics and materials science.
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Extensive Property Example