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Ch.19 - Electrochemistry
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145Non è quello che usi tu?Cambia libro di testo
Capitolo 19, Problema 136b

Predict the anode, cathode, and overall cell reactions when an aqueous solution of each of the following salts is electrolyzed in a cell having inert electrodes. (b) CuCl2

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Identify the ions present in the aqueous solution of CuCl_2. The solution will contain Cu^{2+} and Cl^- ions.
Determine the possible reactions at the anode. In aqueous solutions, the anode reaction can involve the oxidation of Cl^- ions to Cl_2 gas or the oxidation of water to O_2 gas.
Determine the possible reactions at the cathode. The cathode reaction can involve the reduction of Cu^{2+} ions to solid Cu or the reduction of water to H_2 gas.
Compare the standard electrode potentials for the possible reactions at the anode and cathode to determine which reactions are more favorable. The reaction with the more positive potential at the anode and the more negative potential at the cathode will occur.
Write the overall cell reaction by combining the half-reactions from the anode and cathode, ensuring that the electrons are balanced.

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Electrolysis is a chemical process that uses electrical energy to drive a non-spontaneous reaction. In an electrolytic cell, an external voltage is applied to facilitate the movement of ions in an electrolyte solution, leading to the oxidation and reduction reactions at the electrodes. Understanding electrolysis is crucial for predicting the products formed during the electrolysis of compounds like CuCl2.
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