The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128/s at 150 K. a. What is the half-life of the desorption reaction?-

The desorption (leaving of the surface) of a single molecular layer of n-butane from a single crystal of aluminum oxide is found to be first order with a rate constant of 0.128/s at 150 K. b. If the surface is initially completely covered with n-butane at 150 K, how long will it take for 25% of the molecules to desorb (leave the surface)? For 50% to desorb?

The evaporation of a 120-nm film of n-pentane from a single crystal of aluminum oxide is zero order with a rate constant of 1.92⨉1013 molecules/cm²•s at 120 K. a. If the initial surface coverage is 8.9⨉1016 molecules/cm², how long will it take for one-half of the film to evaporate?

Consider the reaction in which HCl adds across the double bond of ethene: HCl + H₂C=CH₂ → H₃C-CH₂Cl The following mechanism, with the accompanying energy diagram, has been suggested for this reaction:

Step 1 HCl + H₂C=CH₂ → H₃C=CH₂⁺ + Cl^-

Step 2 H₃C=CH₂⁺ + Cl^- → H₃C-CH₂Cl

b. What is the expected order of the reaction based on the proposed mechanism?

Consider the reaction in which HCl adds across the double bond of ethene: HCl + H₂C=CH₂ → H₃C-CH₂Cl The following mechanism, with the accompanying energy diagram, has been suggested for this reaction:

Step 1 HCl + H₂C=CH₂ → H₃C=CH₂⁺ + Cl^-

Step 2 H₃C=CH₂⁺ + Cl^- → H₃C-CH₂Cl

a. Based on the energy diagram, determine which step is rate limiting.