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Ch.4 Molecular Compounds
McMurry - Fundamentals of General, Organic, and Biological Chemistry 8th Edition
McMurry8th EditionFundamentals of General, Organic, and Biological ChemistryISBN: 9780134015187Non è quello che usi tu?Cambia libro di testo
Capitolo 4, Problema 38

Which of the following contains a coordinate covalent bond? (Hint: How many covalent bonds would you expect the central atom (underlined/bold) to form?)
a. PbCl2
b. Cu(NH3)42+
c. NH4+

Guida verificata passo dopo passo
1
Identify the definition of a coordinate covalent bond: A coordinate covalent bond occurs when one atom donates both electrons to form a shared pair in a covalent bond, typically seen in complex ions or molecules.
Analyze option a (PbCl₂): Lead (Pb) forms bonds with chlorine (Cl) through regular covalent or ionic bonding. There is no evidence of a coordinate covalent bond here.
Analyze option b (Cu(NH₃)₄²⁺): In this complex ion, the central copper ion (Cu²⁺) is surrounded by four ammonia (NH₃) molecules. Each NH₃ molecule donates a lone pair of electrons to the Cu²⁺ ion, forming coordinate covalent bonds.
Analyze option c (NH₄⁺): The ammonium ion (NH₄⁺) is formed when an NH₃ molecule donates a lone pair of electrons to a hydrogen ion (H⁺). This results in a coordinate covalent bond between NH₃ and H⁺.
Conclude: Based on the analysis, options b (Cu(NH₃)₄²⁺) and c (NH₄⁺) contain coordinate covalent bonds, while option a (PbCl₂) does not.

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Covalent Bonding

Covalent bonding occurs when two atoms share one or more pairs of electrons, allowing each atom to attain a stable electron configuration. This type of bond is typically formed between nonmetals and can be classified into single, double, or triple bonds based on the number of shared electron pairs.
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Covalent Bonds Example 1

Coordinate Covalent Bond

A coordinate covalent bond, also known as a dative bond, is a specific type of covalent bond where one atom donates both electrons to the bond. This often occurs in complex ions or molecules where a central atom, such as a metal, accepts a lone pair of electrons from a donor atom, leading to unique bonding scenarios.
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01:04
Covalent Bonds Example 1

Central Atom and Valency

The central atom in a molecule is typically the atom that forms the most bonds and is often a metal or a nonmetal with a higher valency. Understanding the expected number of bonds that the central atom can form is crucial for predicting the type of bonds present, including whether coordinate covalent bonds are involved in the structure.
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Valence Electrons of Elements (Simplified) Example 1