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Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination
Mullins - Organic Chemistry: A Learner Centered Approach 1st Edition
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Non è quello che usi tu?Cambia libro di testo
Capitolo 12, Problema 86d

Using IUPAC rules, name the following molecules.
(d)

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Identify the longest carbon chain that contains the highest priority functional group. In this case, the longest chain is a cyclohexene ring, which is a six-membered ring with one double bond.
Determine the highest priority functional group. Here, the hydroxyl group (-OH) is the highest priority functional group, making the molecule an alcohol.
Number the carbon atoms in the ring starting from the carbon attached to the hydroxyl group, ensuring that the double bond gets the lowest possible number. The hydroxyl group is on carbon 1, and the double bond is between carbons 2 and 3.
Identify and name any substituents attached to the main chain. There is an isopropyl group attached to carbon 3 of the cyclohexene ring.
Combine the elements of the name, starting with the substituents in alphabetical order, followed by the main chain name with the position of the double bond and the hydroxyl group. The name will be based on the IUPAC rules for naming cycloalkenes with alcohols.

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IUPAC Nomenclature

IUPAC nomenclature is a systematic method for naming organic chemical compounds. It provides rules for identifying the structure of a molecule based on its functional groups, carbon chain length, and branching. Understanding these rules is essential for accurately naming compounds and communicating their structures in the scientific community.
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The different parts of an IUPAC name

Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. Common functional groups include alcohols, carboxylic acids, and amines. Recognizing functional groups is crucial for determining the properties and reactivity of organic compounds, which directly influences their nomenclature.
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Identifying Functional Groups

Carbon Chain Structure

The carbon chain structure refers to the arrangement of carbon atoms in a molecule, which can be linear, branched, or cyclic. The length and configuration of the carbon chain significantly affect the naming of the compound, as IUPAC rules prioritize the longest continuous chain and the position of substituents. Understanding this structure is vital for applying the correct nomenclature.
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Side-Chain Halogenations