Ch. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics

Mullins - Organic Chemistry: A Learner Centered Approach 1st Edition

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Mullins 1st Edition

Ch. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics

Problema 61b

Capitolo 4, Problema 61b

The hydrogenation of alkenes is a reaction we study in Chapter 9.

(b) Is this reaction favored or disfavored in terms of entropy?

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Understand the reaction: Hydrogenation of alkenes involves the addition of hydrogen (H₂) across a carbon-carbon double bond (C=C), converting the alkene into an alkane.

Recall the concept of entropy (ΔS): Entropy is a measure of disorder or randomness in a system. Reactions that increase the number of molecules or increase molecular freedom tend to have a positive ΔS, while reactions that decrease the number of molecules or restrict molecular freedom tend to have a negative ΔS.

Analyze the change in the number of molecules: In the hydrogenation reaction, one molecule of alkene reacts with one molecule of hydrogen gas (H₂) to form a single molecule of alkane. This results in a decrease in the total number of molecules in the system.

Relate the change in the number of molecules to entropy: Since the number of molecules decreases during the reaction, the system becomes more ordered, leading to a decrease in entropy (ΔS < 0).

Conclude whether the reaction is favored or disfavored in terms of entropy: A decrease in entropy (negative ΔS) means the reaction is entropically disfavored. However, note that the overall favorability of the reaction depends on both enthalpy (ΔH) and entropy (ΔS), as described by the Gibbs free energy equation (ΔG = ΔH - TΔS).

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Hydrogenation of Alkenes

Hydrogenation is a chemical reaction that involves the addition of hydrogen (H2) to an alkene, converting it into an alkane. This process typically occurs in the presence of a catalyst, such as palladium or platinum, and results in the saturation of the carbon-carbon double bond. Understanding this reaction is crucial for analyzing its thermodynamic properties, including entropy changes.

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The definition of hydrogenation.

Entropy

Entropy is a measure of the disorder or randomness in a system. In chemical reactions, changes in entropy can indicate whether a reaction is favored or disfavored. Generally, reactions that lead to an increase in the number of gas molecules or greater molecular freedom result in higher entropy, while those that produce more ordered structures, like the hydrogenation of alkenes, tend to decrease entropy.

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Explaining what entropy is.

Thermodynamics of Reactions

The thermodynamics of reactions involves the study of energy changes and the favorability of chemical processes. In the context of hydrogenation, it is important to consider both enthalpy and entropy to determine the overall Gibbs free energy change. A reaction is favored if the Gibbs free energy change is negative, which can occur when the enthalpic benefits outweigh the entropic costs, as seen in the hydrogenation of alkenes.

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Kinetic vs. Thermodynamic Control

Pratica correlata

Domanda del libro di testo

Keto–enol tautomerism is a reaction we discuss in detail in Chapter 19. Estimate the equilibrium constant of this reaction (BDE for C―C π bond = 65 kcal/mol ; for C―O π bond = 85 kcal/mol).

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Reaction (c), on the other hand, is favored (∆G° < 0). Identify the bonds formed and broken and explain this result in light of (a) and (b).

(c)

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Domanda del libro di testo

In light of your answers to parts (b) and (c), where both were shown to be quite favorable, imagine a scenario where either reaction is possible. Of the two, which would you expect to be faster? Which would you expect to be more favored? Explain each in the context of the important thermodynamic and/or kinetic parameters.

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Domanda del libro di testo

Parts (a)–(d) of this assessment assist in the development of what will become a common theme in organic reactions and should be worked in order. [Think carefully about how each question relates to the others.]

(c) Without worrying about the mechanism of the reaction, estimate an equilibrium constant for the following carbonyl addition reaction based on the relative stability of the Lewis bases.

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Domanda del libro di testo

Calculate K_eq for the following acid–base reaction.

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Domanda del libro di testo

Reactions (a) and (b) are disfavored overall (∆G° > 0), yet they are favored based on ∆H°. Identify the bonds formed and broken for (a) and (b).

(b)

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