Domanda del libro di testo
Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions: (iv) H2SO4 , H2O
(g)
1145
views
Ch. 8 - Alkenes 1: Properties and Electrophilic Additions
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471
Non è quello che usi tu?Cambia libro di testoScegli un libro di testo diverso
TOC.tableOfContents
- Ch. 2 - General Chemistry Translated: Finding the Electrons114
- Ch. 3 - Alkanes and Cycloalkanes: Properties and Conformational Analysis109
- Ch. 4 - Acids and Bases/Electron Flow144
- Ch. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics118
- Ch. 6 - Stereoisomerism: Arrangement of Atoms in Space112
- Ch. 7 - Principles of Green (Organic) Chemistry3
- Ch. 8 - Alkenes 1: Properties and Electrophilic Additions158
- Ch. 9 - Alkenes 2: Oxidation and Reduction150
- Ch. 10 - Alkynes: Electrophilic Addition and Redox Reactions101
- Ch. 11 - Properties and Synthesis of Alkyl Halides: Radical Reactions108
- Ch. 12 - Substitution and Elimination: Reactions of Haloalkanes172
- Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination239
- Ch. 14 - Structural Identification 1: Infrared Spectroscopy and Mass Spectrometry54
- Ch. 15 - Structural Identification 2: Nuclear Magnetic Resonance Spectroscopy93
- Ch. 16 - Metals in Organic Chemistry48
- Ch. 17 - Carbonyl Addition Reactions: Aldehydes and Ketones45
- Ch. 18 - Nucleophilic Acyl Substitution 1: Carboxylic Acids18
- Ch. 19 - Nucleophilic Acyl Substitution 2: Carboxylic Acid Derivatives39
- Ch. 20 - Enolates: Carbonyl Addition and Substitution13
- Ch. 21 - Conjugated Systems 1: Stability and Addition Reactions56
- Ch. 22 - Conjugated Systems 2: Pericyclic Reactions54
- Ch. 23 - Benzene 1: Aromatic Stability and Substitution Reactions64
- Ch. 24 - Benzene 2: Reactions Influenced by the Aromatic Ring62
- Ch. 25 - Amines: Structure, Reactions, and Synthesis27
- Ch. 26 - Amino Acids, Proteins, and Peptide Synthesis9
- Ch. 27 - Carbohydrates, Nucleic Acids, and Lipids54
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Non è quello che usi tu?Cambia libro di testo
Tutti i libri di testo
Mullins 1st EditionCh. 8 - Alkenes 1: Properties and Electrophilic AdditionsProblema 61g(vi)
Mullins 1st EditionCh. 8 - Alkenes 1: Properties and Electrophilic AdditionsProblema 61g(vi)Capitolo 7, Problema 61g(vi)
Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions: (vi) 1. BH3 2. H2O2, NaOH
(g) 
Guida verificata passo dopo passo1
Identify the reaction type: The given reagents (1. BH₃, 2. H₂O₂, NaOH) indicate a hydroboration-oxidation reaction. This reaction is used to convert an alkene into an alcohol.
Understand the regioselectivity: Hydroboration-oxidation follows anti-Markovnikov addition, meaning the hydroxyl group (-OH) will attach to the less substituted carbon of the double bond.
Understand the stereochemistry: The addition of BH₃ occurs in a syn fashion, meaning both the boron and hydrogen add to the same side of the alkene. This stereochemistry is retained during the oxidation step, resulting in a syn addition of the hydroxyl group and hydrogen.
Apply the reaction to the given alkene: Identify the double bond in the alkene structure and determine which carbon is less substituted. Attach the hydroxyl group (-OH) to the less substituted carbon and a hydrogen atom to the more substituted carbon.
Draw the product: After determining the regioselectivity and stereochemistry, draw the final product, ensuring the hydroxyl group is on the less substituted carbon and the stereochemistry reflects syn addition.
Risposta video verificata per un problema simile:
Questa soluzione video è stata consigliata dai nostri tutor come utile per risolvere questo problema.
Durata del video:
3mConcetti chiave
Ecco i concetti essenziali che devi comprendere per rispondere correttamente alla domanda.
Hydroboration-Oxidation
Hydroboration-oxidation is a two-step reaction process used to convert alkenes into alcohols. In the first step, borane (BH₃) adds across the double bond of the alkene, resulting in a trialkylborane intermediate. The second step involves oxidation with hydrogen peroxide (H₂O₂) in the presence of a base (NaOH), which converts the boron atom into a hydroxyl group, yielding an alcohol.
Video consigliato:
06:38
General properties of hydroboration-oxidation.
Regioselectivity
Regioselectivity refers to the preference of a chemical reaction to yield one structural isomer over others when multiple products are possible. In hydroboration, the addition of borane occurs in a syn manner, favoring the formation of the less substituted alcohol due to the anti-Markovnikov rule, where the hydroxyl group ends up on the less substituted carbon of the alkene.
Video consigliato:
05:09Heck Reaction
Stereochemistry
Stereochemistry is the study of the spatial arrangement of atoms in molecules and how this affects their chemical behavior. In the hydroboration-oxidation process, the syn addition of BH₃ leads to specific stereochemical outcomes in the final alcohol product, which can influence the reactivity and properties of the resulting compound.
Video consigliato:
Percorso guidato
1:38Polymer Stereochemistry Concept 1
Pratica correlata
Domanda del libro di testo
Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions: (iii) HBr, H2O2
(k)
469
views
Domanda del libro di testo
Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions:(ii) HCl
(g)
1298
views
Domanda del libro di testo
Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions: (v) 1. Hg(OAc)2 , H2O 2. NaBH4
(k)
1284
views
Domanda del libro di testo
Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions: (i) HBr
(g)
1238
views
Domanda del libro di testo
Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions:(ii) HCl
(k)
1284
views