Domanda del libro di testo
Predict the products obtained when d-galactose reacts with each reagent.
(b) NaOH, H2O
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Ch. 23 - Carbohydrates and Nucleic Acids
Wade9th EditionOrganic ChemistryISBN: 9780135213728
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TOC.tableOfContents
- Ch.1 - Structure and Bonding107
- Ch. 2 - Acids and Bases; Functional Groups115
- Ch.3 - Structure and Stereochemistry of Alkanes100
- Ch.4 - The Study of Chemical Reactions99
- Ch.5 - Stereochemistry93
- Ch.6 - Alkyl Halides; Nucleophilic Substitution118
- Ch. 7 - Structure and Synthesis of Alkenes; Elimination158
- Ch.8 - Reactions of Alkenes171
- Ch.9 - Alkynes91
- Ch.10 - Structure and Synthesis of Alcohols143
- Ch.11 - Reactions of Alcohols104
- Ch. 12 - Infrared Spectroscopy and Mass Spectrometry22
- Ch. 13 - Nuclear Magnetic Resonance Spectroscopy45
- Ch. 14 - Ethers, Epoxides, and Thioethers72
- Ch. 15 - Conjugated Systems, Orbital Symmetry, and Ultraviolet Spectroscopy89
- Ch. 16 - Aromatic Compounds74
- Ch. 17 - Reactions of Aromatic Compounds126
- Ch. 18 - Ketones and Aldehydes193
- Ch. 19 - Amines129
- Ch. 20 - Carboxylic Acids77
- Ch. 21 - Carboxylic Acid Derivatives141
- Ch. 22 - Condensations and Alpha Substitutions of Carbonyl Compounds175
- Ch. 23 - Carbohydrates and Nucleic Acids93
- Ch. 24 - Amino Acids, Peptides, and Proteins54
Capitolo 23, Problema 52d
Predict the products obtained when D-galactose reacts with each reagent.
(d) Ag(NH3)2+ –OH
Guida verificata passo dopo passo1
Identify the functional groups present in D-galactose. D-galactose is an aldose sugar, meaning it contains an aldehyde group (-CHO) at the anomeric carbon and multiple hydroxyl (-OH) groups.
Understand the role of the reagent Ag(NH3)2+ (Tollens' reagent). Tollens' reagent is a mild oxidizing agent that specifically oxidizes aldehydes to carboxylic acids, while leaving other functional groups (like alcohols) unchanged.
Write the reaction mechanism. The aldehyde group (-CHO) in D-galactose will be oxidized to a carboxylic acid group (-COOH) by the Tollens' reagent. This reaction involves the transfer of electrons from the aldehyde to the silver ion (Ag+), reducing Ag+ to metallic silver (Ag).
Predict the product. The oxidation of the aldehyde group in D-galactose will result in the formation of D-galactonic acid, where the aldehyde is replaced by a carboxylic acid group. The hydroxyl groups on the other carbons remain unchanged.
Summarize the reaction. The reaction of D-galactose with Ag(NH3)2+ - OH results in the formation of D-galactonic acid and metallic silver as a byproduct, which may appear as a silver mirror on the reaction vessel.
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Concetti chiave
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D-Galactose Structure
D-galactose is a monosaccharide with a specific configuration at its hydroxyl groups. It is an aldohexose, meaning it contains an aldehyde group and six carbon atoms. Understanding its structure is crucial for predicting how it will react with various reagents, as the orientation of its functional groups influences the reaction pathways.
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06:47
Monosaccharides - D and L Isomerism
Oxidation-Reduction Reactions
The reaction of d-galactose with Ag(NH3)2+ involves an oxidation-reduction process, where the aldehyde group of galactose is oxidized to a carboxylic acid. In this context, silver ions act as an oxidizing agent, facilitating the transfer of electrons. Recognizing this type of reaction is essential for predicting the products formed during the interaction.
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00:54Distinguishing between Oxidation and Reduction
Silver Ammonia Complex
Ag(NH3)2+ is a silver ammonia complex commonly used in organic chemistry as a mild oxidizing agent. It is particularly effective in oxidizing aldehydes to carboxylic acids without affecting other functional groups. Understanding the role of this complex helps in predicting the outcome of the reaction with d-galactose and the specific products formed.
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05:02Coordination Complexes
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