Skip to main content
Ch.11 - Liquids and Intermolecular Forces
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
11장, 문제 34a,c

Based on their composition and structure, list CH2Cl2, CH3CH2CH3, and CH3CH2OH in order of (a) increasing intermolecular forces (c) increasing surface tension

검증된 단계별 안내
1
Identify the molecular structure of each compound: CH\(_2\)Cl\(_2\) (dichloromethane), CH\(_3\)CH\(_2\)CH\(_3\) (propane), and CH\(_3\)CH\(_2\)OH (ethanol).
Consider the types of intermolecular forces present in each compound. CH\(_2\)Cl\(_2\) has dipole-dipole interactions due to its polar nature, CH\(_3\)CH\(_2\)CH\(_3\) has only London dispersion forces as it is nonpolar, and CH\(_3\)CH\(_2\)OH has hydrogen bonding due to the presence of an -OH group.
Recall that surface tension is influenced by the strength of intermolecular forces: stronger intermolecular forces result in higher surface tension.
Compare the strength of intermolecular forces: hydrogen bonding (strongest) > dipole-dipole interactions > London dispersion forces (weakest).
Arrange the compounds in order of increasing surface tension based on the strength of their intermolecular forces: CH\(_3\)CH\(_2\)CH\(_3\) (weakest) < CH\(_2\)Cl\(_2\) < CH\(_3\)CH\(_2\)OH (strongest).

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
1m
도움이 되었나요?

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Surface Tension

Surface tension is a physical property of liquids that describes the elastic-like force at the surface, caused by the cohesive forces between liquid molecules. It is influenced by intermolecular forces, such as hydrogen bonding and van der Waals forces. Liquids with stronger intermolecular forces typically exhibit higher surface tension, as the molecules at the surface are pulled inward more strongly.
추천 영상:
가이드 코스
03:13
Intermolecular Forces and Properties

Intermolecular Forces

Intermolecular forces are the forces of attraction or repulsion between molecules. They include hydrogen bonds, dipole-dipole interactions, and London dispersion forces. The type and strength of these forces significantly affect the physical properties of substances, including boiling point, melting point, and surface tension. For example, molecules with hydrogen bonding, like alcohols, generally have higher surface tension than non-polar molecules.
추천 영상:
가이드 코스
01:59
Intermolecular vs Intramolecular Forces

Molecular Structure and Polarity

The molecular structure and polarity of a compound play a crucial role in determining its physical properties. Polar molecules, which have a significant difference in electronegativity between atoms, tend to have stronger intermolecular forces compared to non-polar molecules. In the context of the given compounds, the presence of polar functional groups, such as hydroxyl (-OH) in CH3CH2OH, increases surface tension due to enhanced hydrogen bonding compared to non-polar hydrocarbons.
추천 영상:
가이드 코스
02:38
Molecular Polarity