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Ch.12 - Solids and Modern Materials
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
모든 교과서Brown 14th EditionCh.12 - Solids and Modern Materials문제 54
12장, 문제 54

Which of the following statements does not follow from the fact that the alkali metals have relatively weak metal–metal bonding? (a) The alkali metals are less dense than other metals. (b) The alkali metals are soft enough to be cut with a knife. (c) The alkali metals are more reactive than other metals. (d) The alkali metals have higher melting points than other metals. (e) The alkali metals have low ionization energies.

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1
Identify the general properties of alkali metals related to their weak metal-metal bonding. These properties include being soft, having low densities, low melting points, and low ionization energies.
Analyze each statement to see if it logically follows from the weak metal-metal bonding of alkali metals. Weak bonding generally leads to easier deformation (softness), lower density, and lower energy required to remove an electron (ionization energy).
Consider the statement about reactivity. Alkali metals are known for their high reactivity, which is influenced by their low ionization energies, allowing them to lose electrons easily.
Evaluate the statement regarding the melting points of alkali metals. Weak metal-metal bonding would suggest lower melting points because less energy is required to overcome the bonding between atoms.
Determine which statement does not logically follow from the premise of weak metal-metal bonding. A statement that contradicts the expected properties derived from weak bonding would be the correct choice.

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주요 개념

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Metal-Metal Bonding

Metal-metal bonding refers to the interactions between metal atoms in a solid. In alkali metals, these bonds are relatively weak due to their single valence electron, which leads to a less cohesive structure. This weakness contributes to their unique physical properties, such as lower density and softness compared to other metals.
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03:12
Transition Metals

Reactivity of Alkali Metals

Alkali metals are known for their high reactivity, which is primarily due to their low ionization energies. This means they can easily lose their single valence electron to form positive ions. Their reactivity increases down the group, making them more reactive than many other metals, which is a key characteristic of these elements.
추천 영상:
가이드 코스
03:12
Transition Metals

Melting Points and Density

The melting points of alkali metals are generally lower than those of other metals, which is attributed to their weak metal-metal bonding. Additionally, their low density is a result of their atomic structure and the presence of these weak bonds. Understanding these properties helps in predicting the behavior of alkali metals in various conditions.
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가이드 코스
04:29
Boiling Point and Melting Point
관련 실천
교과서 질문

Which would you expect to be the more ductile element, (a) Ag or Mo? (b) Zn or Si? In each case explain your reasoning.

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교과서 질문

Repeat Exercise 12.51 for a linear chain of eight lithium atoms. (f) How does the HOMO–LUMO energy gap for this case compare to that of the four-atom case?

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교과서 질문

Repeat Exercise 12.51 for a linear chain of eight lithium atoms. (b) How many nodes are in the lowest-energy molecular orbital? (c) How many nodes are in the highestenergy molecular orbital? (d) How many nodes are in the highest-energy occupied molecular orbital (HOMO)? (e) How many nodes are in the lowest-energy unoccupied molecular orbital (LUMO)?

교과서 질문

Tausonite, a mineral composed of Sr, O, and Ti, has the cubic unit cell shown in the drawing. (a) What is the empirical formula of this mineral?

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교과서 질문
For each of the following groups, which metal would you expect to have the highest melting point: (b) rubidium, molybdenum, or indium?
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