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Ch.5 - Thermochemistry
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
5장, 문제 46b

At one time, a common means of forming small quantities of oxygen gas in the laboratory was to heat KClO3: 2 KClO3(s) → 2 KCl(s) + 3 O2(g) ΔH = -89.4 kJ For this reaction, calculate H for the formation of (b) 10.4 g of KCl.

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1
Identify the molar mass of KCl by adding the atomic masses of K (potassium) and Cl (chlorine).
Calculate the number of moles of KCl in 10.4 g using the formula: \( \text{moles of KCl} = \frac{\text{mass of KCl}}{\text{molar mass of KCl}} \).
Use the stoichiometry of the balanced chemical equation to determine the relationship between moles of KCl and the enthalpy change (\( \Delta H \)).
Calculate the enthalpy change for the formation of the calculated moles of KCl using the relationship: \( \Delta H = \text{moles of KCl} \times \frac{-89.4 \text{ kJ}}{2 \text{ moles of KCl}} \).
Express the final enthalpy change in kJ for the formation of 10.4 g of KCl.

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced equation. It allows us to determine the relationships between the amounts of substances involved in a reaction, such as how many grams of a product can be formed from a given mass of reactants. In this case, stoichiometry will help us relate the mass of KCl produced to the amount of KClO3 reacted.
추천 영상:
가이드 코스
01:16
Stoichiometry Concept

Enthalpy Change (ΔH)

Enthalpy change (ΔH) is a measure of the heat energy absorbed or released during a chemical reaction at constant pressure. In the given reaction, ΔH = -89.4 kJ indicates that the reaction is exothermic, meaning it releases energy. Understanding ΔH is crucial for calculating the energy associated with the formation of products, such as KCl, from the reactants.
추천 영상:
가이드 코스
02:34
Enthalpy of Formation

Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is essential for converting between the mass of a substance and the number of moles, which is necessary for stoichiometric calculations. To find the amount of KCl formed, we need to know its molar mass to convert the given mass (10.4 g) into moles for further calculations.
추천 영상:
가이드 코스
02:11
Molar Mass Concept
관련 실천
교과서 질문

At one time, a common means of forming small quantities of oxygen gas in the laboratory was to heat KClO3: 2 KClO3(s) → 2 KCl(s) + 3 O2(g) ΔH = -89.4 kJ (c) The decomposition of KClO3 proceeds spontaneously when it is heated. Do you think that the reverse reaction, the formation of KClO3 from KCl and O2, is likely to be feasible under ordinary conditions? Explain your answer.

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교과서 질문

Consider the combustion of liquid methanol, CH3OH(l): CH3OH(l) + 3/2 O2(g) → CO2(g) + 2 H2O(l) ΔH = -726.5 kJ (b) Balance the forward reaction with whole-number coefficients. What is ΔH for the reaction represented by this equation?

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교과서 질문

When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates Ag+(aq) + Cl-(aq) → AgCl(s) H = -65.5 kJ (a) Calculate H for the production of 0.450 mol of AgCl by this reaction. (b) Calculate H for the production of 9.00 g of AgCl. (c) Calculate H when 9.25⨉10-4 mol of AgCl dissolves in water.

861
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교과서 질문

At one time, a common means of forming small quantities of oxygen gas in the laboratory was to heat KClO3: 2 KClO3(s) → 2 KCl(s) + 3 O2(g) ΔH = -89.4 kJ For this reaction, calculate H for the formation of (a) 1.36 mol of O2

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교과서 질문

Consider the following reaction: 2 CH3OH(g) → 2 CH4(g) + O2(g) ΔH = +252.8 kJ (d) How many kilojoules of heat are released when 38.5 g of CH4(g) reacts completely with O2(g) to form CH3OH(g) at constant pressure?

458
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교과서 질문

Consider the combustion of liquid methanol, CH3OH(l): CH3OH(l) + 3/2 O2(g) → CO2(g) + 2 H2O(l) ΔH = -726.5 kJ (a) What is the enthalpy change for the reverse reaction?

744
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