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Ch.6 - Electronic Structure of Atoms
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
6장, 문제 44b

The hydrogen atom can absorb light of wavelength 1094 nm. (b) Determine the final value of n associated with this absorption.

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1
Identify the formula to use: The Rydberg formula for hydrogen absorption is \( \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \), where \( \lambda \) is the wavelength, \( R_H \) is the Rydberg constant (1.097 \(\times\) 10^7 \(\text{ m}\)^{-1}), \( n_1 \) is the initial energy level, and \( n_2 \) is the final energy level.
Convert the wavelength from nanometers to meters: Since 1 nm = 1 \(\times\) 10^{-9} m, convert 1094 nm to meters.
Assume the initial energy level \( n_1 \) is 1, as the problem does not specify it, and this is a common assumption for absorption from the ground state.
Rearrange the Rydberg formula to solve for \( n_2 \): \( n_2 = \sqrt{\frac{1}{\frac{1}{n_1^2} - \frac{\lambda}{R_H}}} \).
Substitute the known values into the equation: Use the converted wavelength and the Rydberg constant to calculate \( n_2 \).

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Energy of Photons

The energy of a photon is directly related to its wavelength, described by the equation E = hc/λ, where E is energy, h is Planck's constant, c is the speed of light, and λ is the wavelength. For the hydrogen atom, when it absorbs a photon, the energy from the photon is used to excite an electron to a higher energy level.
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가이드 코스
01:40
Photon Energy Formulas

Quantum Energy Levels

In a hydrogen atom, electrons occupy discrete energy levels, denoted by the principal quantum number n. The energy associated with each level can be calculated using the formula E_n = -13.6 eV/n². When a photon is absorbed, the electron transitions from a lower energy level (n_initial) to a higher one (n_final), and the difference in energy corresponds to the energy of the absorbed photon.
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가이드 코스
02:55
Principal Quantum Number

Balmer and Rydberg Formulas

The Rydberg formula allows for the calculation of the wavelengths of spectral lines in hydrogen and is given by 1/λ = R_H(1/n_final² - 1/n_initial²). This formula is essential for determining the final energy level (n_final) after absorption, as it relates the wavelength of light absorbed to the transition between quantum states of the hydrogen atom.
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가이드 코스
01:00
Balmer Series Example