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Ch.9 - Molecular Geometry and Bonding Theories
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
모든 교과서Brown 14th EditionCh.9 - Molecular Geometry and Bonding Theories문제 93b
9장, 문제 93b

An AB5 molecule adopts the geometry shown here. (b) Do you think there are any nonbonding electron pairs on atom A?
3D model of an AB5 molecule illustrating its molecular geometry.

검증된 단계별 안내
1
Identify the molecular geometry of the AB5 molecule shown in the image. The geometry appears to be trigonal bipyramidal.
Recall that in a trigonal bipyramidal geometry, the central atom (A) is surrounded by five atoms (B) with three atoms in the equatorial plane and two atoms in the axial positions.
Determine the electron domain geometry around the central atom (A). For a molecule with five bonding pairs and no lone pairs, the electron domain geometry is also trigonal bipyramidal.
Consider the presence of nonbonding electron pairs on the central atom (A). In a trigonal bipyramidal geometry, if there were any nonbonding electron pairs, they would occupy equatorial positions to minimize electron pair repulsion.
Conclude that since the molecule adopts a trigonal bipyramidal geometry with five bonding pairs and no lone pairs, there are no nonbonding electron pairs on atom A.

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. In the case of an AB5 molecule, where 'A' is the central atom and 'B' represents five surrounding atoms, the geometry is typically trigonal bipyramidal. Understanding this geometry is crucial for predicting the spatial orientation of the atoms and the potential presence of lone pairs.
추천 영상:
가이드 코스
01:33
Molecular Geometry with Two Electron Groups

VSEPR Theory

Valence Shell Electron Pair Repulsion (VSEPR) theory is a model used to predict the geometry of molecules based on the repulsion between electron pairs in the valence shell of the central atom. According to VSEPR, electron pairs, whether bonding or nonbonding, will arrange themselves to minimize repulsion, which helps determine the molecular shape and the presence of lone pairs.
추천 영상:
가이드 코스
02:13
Molecular Shapes and VSEPR

Lone Pairs

Lone pairs are pairs of valence electrons that are not involved in bonding and are localized on a single atom. In the context of the AB5 molecule, the presence of lone pairs on atom A would influence its geometry and the angles between the surrounding B atoms. Identifying lone pairs is essential for accurately predicting molecular shape and reactivity.
추천 영상:
가이드 코스
01:33
Lone Pair Positions
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