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Ch.9 - Molecular Geometry and Bonding Theories
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
9장, 문제 77

How would we describe a substance that contains only paired electrons and is weakly repelled by a magnetic field? Which of the following ions would you expect to possess similar characteristics: H2-, Ne2+, F2, O22 +?

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Identify the type of magnetic behavior described: A substance that contains only paired electrons and is weakly repelled by a magnetic field exhibits diamagnetic behavior. Diamagnetism occurs when all of the electrons in the substance are paired, resulting in no net magnetic moment.
Understand the electron configuration of the ions: To determine if an ion is diamagnetic, check if all its electrons are paired. An ion with all electrons paired will be diamagnetic and thus weakly repelled by a magnetic field.
Analyze the electron configuration of H2-: H2- has an extra electron compared to the H2 molecule, leading to an unpaired electron. Therefore, H2- is not diamagnetic.
Analyze the electron configuration of Ne2+: Ne2+ would involve the removal of electrons from a Neon atom, which originally has all paired electrons. Depending on the number of electrons removed, if it results in all electrons still being paired, Ne2+ could be diamagnetic.
Analyze the electron configuration of F2 and O22+: F2 has unpaired electrons in its molecular orbital configuration, making it paramagnetic, not diamagnetic. O22+ (peroxide ion) also has unpaired electrons, specifically in its antibonding orbitals, making it paramagnetic as well.

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주요 개념

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Paired Electrons

Paired electrons refer to two electrons occupying the same orbital with opposite spins. In a substance where all electrons are paired, there are no unpaired electrons to contribute to magnetic properties, resulting in a diamagnetic character. Such substances are weakly repelled by magnetic fields, as they do not have a net magnetic moment.
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가이드 코스
00:47
Valence Shell Electron Pair Repulsion Theory

Diamagnetism

Diamagnetism is a form of magnetism that occurs in materials with all electrons paired, leading to a lack of net magnetic moment. When exposed to a magnetic field, diamagnetic substances create an opposing magnetic field, causing them to be weakly repelled. This property is crucial for identifying substances that behave similarly in magnetic fields.
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가이드 코스
01:33
Paramagnetism and Diamagnetism

Ionic Characteristics

Ionic characteristics refer to the properties of ions, which are charged species formed when atoms gain or lose electrons. The stability and electron configuration of ions like H2-, Ne2+, F2, and O22+ can influence their magnetic properties. Understanding the electron configurations of these ions helps predict whether they will exhibit diamagnetic behavior based on the pairing of their electrons.
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가이드 코스
02:59
Acid Characteristics