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Ch.10 - Gases: Their Properties & Behavior
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145당신이 사용하는 게 아니라요?교과서 변경
10장, 문제 149d

Chemical explosions are characterized by the instantaneous release of large quantities of hot gases, which set up a shock wave of enormous pressure (up to 700,000 atm) and velocity (up to 20,000 mi/h). For example, explosion of nitroglycerin (C3H5N3O9) releases four gases, A, B, C, and D:
n C3H5N3O9(l) a A(g) + b B(g) + c C(g) + d D(g)
Assume that the explosion of 1 mol (227 g) of nitroglycerin releases gases with a temperature of 1950 °C and a volume of 1323 L at 1.00 atm pressure.
(d) When gases C and D were passed through a hot tube of powdered copper, gas C reacted to form CuO. The remaining gas, D, was collected in a third 500.0-mL flask and found to have a mass of 0.168 g and a pressure of 223 mm Hg at 25 °C. How many moles each of C and D were present, and what are their likely identities?

검증된 단계별 안내
1
Step 1: Convert the pressure of gas D from mm Hg to atm using the conversion factor (1 atm = 760 mm Hg).
Step 2: Use the ideal gas law, PV = nRT, to calculate the number of moles of gas D. Remember to use the appropriate values for R (0.0821 L atm/mol K) and convert the temperature from Celsius to Kelvin (K = °C + 273.15).
Step 3: Calculate the total moles of gases C and D initially present using the ideal gas law for the combined volume, temperature, and pressure given for the explosion.
Step 4: Subtract the moles of gas D from the total moles calculated in Step 3 to find the moles of gas C.
Step 5: Identify the likely chemical identities of gases C and D based on their chemical behavior (reaction with copper to form CuO) and typical products of nitroglycerin decomposition.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
21m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law is essential for calculating the number of moles of gases produced in a reaction, as it allows us to determine how many moles correspond to a given volume and pressure at a specific temperature.
추천 영상:
가이드 코스
01:15
Ideal Gas Law Formula

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. Understanding stoichiometry is crucial for determining the amounts of gases C and D produced from the decomposition of nitroglycerin, as it provides the ratios needed to relate the moles of reactants to the moles of products.
추천 영상:
가이드 코스
01:16
Stoichiometry Concept

Gas Collection and Analysis

Gas collection and analysis involve measuring the properties of gases, such as mass, volume, and pressure, to identify their composition. In this scenario, the mass and pressure of gas D are given, which can be used alongside the Ideal Gas Law to calculate the number of moles and potentially identify the gas based on its properties.
추천 영상:
가이드 코스
06:11
Dimensional Analysis
관련 실천
교과서 질문

Chemical explosions are characterized by the instantaneous release of large quantities of hot gases, which set up a shock wave of enormous pressure (up to 700,000 atm) and velocity (up to 20,000 mi/h). For example, explosion of nitroglycerin (C3H5N3O9) releases four gases, A, B, C, and D:

n C3H5N3O9(l) a A(g) + b B(g) + c C(g) + d D(g)

Assume that the explosion of 1 mol (227 g) of nitroglycerin releases gases with a temperature of 1950 °C and a volume of 1323 L at 1.00 atm pressure.

(e) Write a balanced equation for the explosion of nitroglycerin.

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교과서 질문

Combustion analysis of 0.1500 g of methyl tert-butyl ether, an octane booster used in gasoline, gave 0.3744 g of CO2 and 0.1838 g of H2O. When a flask having a volume of 1.00 L was evacuated and then filled with methyl tertbutyl ether vapor at a pressure of 100.0 kPa and a temperature of 54.8 °C, the mass of the flask increased by 3.233 g. (a) What is the empirical formula of methyl tert-butyl ether?

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교과서 질문
The Rankine temperature scale used in engineering is to the Fahrenheit scale as the Kelvin scale is to the Celsius scale. That is, 1 Rankine degree is the same size as 1 Fahrenheit degree, and 0 °R = absolute zero. (b) What is the value of the gas constant R on the Rankine scale in 1L ~ atm2>1°R ~ mol2? (c) Use the van der Waals equation to determine the pressure inside a 400.0-mL vessel that contains 2.50 mol of CH4 at a temperature of 525 °R. For CH4, a = 2.253 1L2 ~ atm2>mol2 and b = 0.04278 L>mol.
597
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교과서 질문
Combustion analysis of 0.1500 g of methyl tert-butyl ether, an octane booster used in gasoline, gave 0.3744 g of CO2 and 0.1838 g of H2O. When a flask having a volume of 1.00 L was evacuated and then filled with methyl tertbutyl ether vapor at a pressure of 100.0 kPa and a temperature of 54.8 °C, the mass of the flask increased by 3.233 g. (b) What is the molecular weight and molecular formula of methyl tert-butyl ether?
300
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교과서 질문

Isooctane, C8H18, is the component of gasoline from which the term octane rating derives. (d) How many moles of air are necessary for the combustion of 1 mol of isooctane, assuming that air is 21.0% O2 by volume? What is the volume in liters of this air at STP?

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