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Ch.18 - Free Energy and Thermodynamics
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831당신이 사용하는 게 아니라요?교과서 변경
18장, 문제 28

Which of these processes are nonspontaneous? Are the nonspontaneous processes impossible? a. a bike going up a hill b. a meteor falling to Earth c. obtaining hydrogen gas from liquid water d. a ball rolling down a hill

검증된 단계별 안내
1
1. A nonspontaneous process is one that does not occur naturally without the input of energy. It's important to note that nonspontaneous does not mean impossible, it just means that energy must be added to the system for the process to occur.
2. For option a, a bike going up a hill, this is a nonspontaneous process. It requires an input of energy (in this case, the cyclist's effort) to make the bike go uphill against the force of gravity.
3. For option b, a meteor falling to Earth, this is a spontaneous process. It happens naturally due to the force of gravity pulling the meteor towards the Earth.
4. For option c, obtaining hydrogen gas from liquid water, this is a nonspontaneous process. It requires an input of energy, usually in the form of electricity, to break the bonds in water molecules and form hydrogen gas.
5. For option d, a ball rolling down a hill, this is a spontaneous process. It happens naturally due to the force of gravity pulling the ball downhill.

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주요 개념

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Spontaneity of Processes

A spontaneous process is one that occurs naturally under given conditions without the need for external energy. These processes tend to increase the overall entropy of the system and its surroundings. In contrast, nonspontaneous processes require energy input to occur, indicating that they do not favor the direction of change without assistance.
추천 영상:
가이드 코스
04:20
Spontaneity of Processes

Energy and Work

In chemistry, energy is the capacity to do work, and it plays a crucial role in determining whether a process is spontaneous or nonspontaneous. For example, moving a bike uphill requires work against gravitational forces, making it nonspontaneous. Understanding the relationship between energy, work, and spontaneity helps clarify why certain processes need energy input.
추천 영상:
가이드 코스
01:52
Work Function Calculation Example

Thermodynamics and Entropy

Thermodynamics is the study of energy transformations, and entropy is a measure of disorder in a system. Nonspontaneous processes often lead to a decrease in entropy, which is unfavorable in natural systems. By analyzing the changes in entropy and energy, one can determine the spontaneity of a process and whether it can occur without external influence.
추천 영상:
가이드 코스
02:46
Entropy in Thermodynamics