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Ch.6 Carbohydrates Life's Sweet Molecules
Frost - General, Organic and Biological Chemistry 4th Edition
Frost4th EditionGeneral, Organic and Biological ChemistryISBN: 9780134988696당신이 사용하는 게 아니라요?교과서 변경
3장, 문제 84

Glycogen and amylopectin are both branched polymers of glucose. Read the descriptions of each in Section 6.6. Which molecule has a more compact structure? Explain.

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Step 1: Understand the structure of glycogen. Glycogen is a highly branched polymer of glucose, primarily found in animals. It consists of α(1→4) linked glucose units with α(1→6) linkages at the branch points.
Step 2: Understand the structure of amylopectin. Amylopectin is a component of starch, found in plants, and is also a branched polymer of glucose. It has a similar structure to glycogen, with α(1→4) linked glucose units and α(1→6) linkages at the branch points, but it is less branched than glycogen.
Step 3: Compare the branching frequency. Glycogen has branches approximately every 8-12 glucose units, while amylopectin has branches approximately every 24-30 glucose units.
Step 4: Analyze the impact of branching on compactness. The more frequent branching in glycogen results in a more compact and dense structure compared to amylopectin.
Step 5: Conclude which molecule is more compact. Based on the branching frequency and structure, glycogen is more compact than amylopectin due to its higher degree of branching.

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Glycogen Structure

Glycogen is a highly branched polymer of glucose, primarily found in animals. Its structure allows for rapid release of glucose when energy is needed, as the numerous branching points provide multiple sites for enzymatic action. This extensive branching contributes to its compactness, enabling efficient storage in limited space.
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Structural Formula Concept 2

Amylopectin Structure

Amylopectin is a component of starch and also a branched polymer of glucose, but it has fewer branches compared to glycogen. The branching occurs approximately every 24 to 30 glucose units, resulting in a less compact structure than glycogen. This difference in branching frequency affects its solubility and the way it is stored in plants.
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Structural Formula Concept 2

Compactness in Polymers

The compactness of a polymer like glycogen or amylopectin is influenced by its branching structure. More branches typically lead to a more compact arrangement, as seen in glycogen, which can fold and pack tightly. In contrast, the less frequent branching in amylopectin results in a more extended and less dense structure, affecting its physical properties and storage efficiency.
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Intro To Carbohydrate Metabolism Concept 1
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교과서 질문

Carbohydrates are abbreviated using a three-letter abbreviation followed by their glycosidic bond type. For example, maltose and sucrose can be written respectively as

Provide the structure for the O-type blood carbohydrate set given the following abbreviation:

L-Fucα (1→2) Galß(1→4)GlcNAc

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교과서 질문

The structure of sucralose, found in the artificial sweetener Splenda, is shown in the figure. It consists of a chlorinated disaccharide made up of galactose and fructose. In its structure shown,

(a) identify the galactose unit and the fructose unit.

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교과서 질문

Our bodies cannot digest cellulose because we lack the enzyme cellulase. Why is cellulose an important part of a healthy diet if we cannot digest it?

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교과서 질문

The glycosidic bond in a disaccharide was determined to be α(1→6). Hydrolysis of the disaccharide produced one galactose and one fructose. Draw the structure of the disaccharide.

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교과서 질문

On an exam, a student was asked to draw the Fischer projection of L-glucose, but he had only memorized the structure of D-glucose. He wrote the structure of D-glucose and switched the hydroxyl group on C5 from the right to the left. Was his answer correct? If not, what is the name of the aldose that he drew?

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교과서 질문

The shell of a shrimp is composed of chitin. If you eat a boiled shrimp without removing the shell, will your body break the shell down into its component sugars? Explain. (Hint: Compare chitin’s structure to that of amylose and cellulose.)

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