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Ch 18: Thermal Properties of Matter
Young & Freedman Calc - University Physics 14th Edition
Young & Freedman Calc14th EditionUniversity PhysicsISBN: 9780321973610당신이 사용하는 게 아니라요?교과서 변경
18장, 문제 35

At what temperature is the root-mean-square speed of nitrogen molecules equal to the root-mean-square speed of hydrogen molecules at 20.020.0°C? (Hint: Appendix D shows the molar mass (in g/mol) of each element under the chemical symbol for that element. The molar mass of H2 is twice the molar mass of hydrogen atoms, and similarly for N2.)

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First, understand the concept of root-mean-square speed (v_rms) for gas molecules, which is given by the formula: 3kTm, where k is the Boltzmann constant, T is the temperature in Kelvin, and m is the mass of a molecule.
Next, convert the given temperature of hydrogen molecules from Celsius to Kelvin using the formula: T=TC+273.15. For hydrogen at 20.0°C, this becomes 293.15 K.
Determine the molar mass of nitrogen (N2) and hydrogen (H2) using Appendix D. The molar mass of nitrogen atoms is approximately 14 g/mol, so for N2 it is 28 g/mol. The molar mass of hydrogen atoms is approximately 1 g/mol, so for H2 it is 2 g/mol.
Set up the equation for the root-mean-square speed equality: 3kTNmN = 3k293.15mH, where TN is the temperature of nitrogen molecules, mN is the mass of a nitrogen molecule, and mH is the mass of a hydrogen molecule.
Solve for TN by equating the expressions and simplifying: TN=mNmH×293.15. Substitute the known values for mN and mH to find the temperature at which the root-mean-square speeds are equal.

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주요 개념

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Root-Mean-Square Speed

The root-mean-square speed is a measure of the average speed of particles in a gas, derived from the kinetic theory of gases. It is calculated using the formula v_rms = sqrt(3kT/m), where k is the Boltzmann constant, T is the temperature in Kelvin, and m is the mass of a molecule. This concept helps compare the speeds of different gas molecules at varying temperatures.
추천 영상:
05:21
Root-Mean-Square Speed of Ideal Gases

Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is crucial for calculating the mass of individual molecules, which is needed to determine their root-mean-square speed. For diatomic molecules like H2 and N2, the molar mass is twice that of the individual atoms, reflecting the combined mass of the two atoms in the molecule.
추천 영상:
20:32
Mass Spectrometers

Temperature Conversion

Temperature conversion is essential for calculations involving the kinetic theory of gases, as temperatures must be in Kelvin. To convert from Celsius to Kelvin, add 273.15 to the Celsius temperature. This conversion ensures that the temperature is in the correct unit for use in the root-mean-square speed formula, allowing for accurate comparisons between different gases.
추천 영상:
07:46
Unit Conversions
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