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15. Chemical Kinetics - Part 3 of 3
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Problem 1
Problem 2
Problem 3
Problem 4
Problem 5
Problem 6
Problem 7
Problem 8
Problem 9
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Problem 11
15. Chemical Kinetics - Part 3 of 3
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15. Chemical Kinetics / Rate Law / Problem 1
Problem 1
The following reaction occurs in basic solution:
OBr
—
(aq) + PH
3
(aq) → OH
—
(aq) + PH
2
Br(aq)
Given the initial rate data for the reaction at 25 °C,
Determine the
rate law for the reaction and
numerical value of the rate constant, k, with correct units.
A
rate = k[OBr
−
][PH
3
][OH
−
]
k = 1.2×10
7
M
−2
·s
−1
B
rate = k[OBr
−
]
2
[PH
3
][OH
−
]
k = 8.0×10
8
M
−3
·s
−1
C
rate = k([OBr
−
][PH
3
])/[OH
−
]
k = 0.12 s
−1
D
rate = k[OBr
−
][PH
3
]
2
[OH
−
]
k = 6.0×10
8
M
−3
·s
−1
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