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Shown in the mechanism below is the catalyzed decomposition of hydrogen peroxide. Determine the catalyst/s and the reaction intermediate/s.
Step 1. H2O2 + 2 Br- + 2 H+ → 2 H2O + Br2
Step 2. H2O2 + Br2 → 2 Br- + 2 H+ + O2
Consider the following reaction mechanism:
OCl–(aq) + H2O(l) ⇌ HOCl(aq) + OH–(aq) (fast equilibrium)
I–(aq) + HOCl(aq) → HOI(aq) + Cl–(aq) (slow)
HOI(aq) + OH–(aq) → H2O(l) + OI–(aq) (fast)
Determine the catalyst and intermediate(s).
A. No catalyst, intermediate = HOCl, HOI, OH–
B. No catalyst, intermediates = H2O, HOCl, HOI, OH–
C. Catalyst = H2O, intermediates = HOCl, HOI, OH–
D. Catalyst = H2O, intermediate = HOCl, HOI
The reaction H2(g) + I2(g) → 2 HI(g) was thought to occur via a two-step mechanism:
Step 1: I2(g) ⇌ 2 I(g) (fast equilibrium)
Step 2: 2 I(g) + H2(g) → 2 HI(g) (slow)
Determine the rate law for the reaction.
What is the rate law for the overall reaction represented by the diagram below where the black circles are carbon and red circles are oxygen if the 2nd step is the rate-determining step?
Consider the reaction below:
A + C2 → AC2
The reaction is first-order in A and first-order in C2.
Two mechanisms are proposed for the reaction:
Mechanism 1 (single-step):
A + C2 → AC2
Mechanism 2:
B + C2 → BC + C slow
A + BC → AB + C fast
AB + 2 C → AC2 + B fast
Are both mechanisms valid? If yes why?
Identify the order of the reaction based on the energy diagram and proposed mechanism:
Step 1: AB + C → AC + B
Step 2: AC + B → ACB
Consider this three-step mechanism for a reaction:
Cl2 (g) k1⇌k2 2 Cl (g) Fast
Cl (g) + CHCl3 (g) →k3 HCl (g) + CCl3 (g) Slow
Cl (g) + CCl3 (g) →k4 CCl4 (g) Fast
c. What is the predicted rate law?