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Shown in the mechanism below is the catalyzed decomposition of hydrogen peroxide. Determine the catalyst/s and the reaction intermediate/s.
Step 1. H2O2 + 2 Br- + 2 H+ → 2 H2O + Br2
Step 2. H2O2 + Br2 → 2 Br- + 2 H+ + O2
Consider the following reaction mechanism:
OCl–(aq) + H2O(l) ⇌ HOCl(aq) + OH–(aq) (fast equilibrium)
I–(aq) + HOCl(aq) → HOI(aq) + Cl–(aq) (slow)
HOI(aq) + OH–(aq) → H2O(l) + OI–(aq) (fast)
Determine the catalyst and intermediate(s).
A. No catalyst, intermediate = HOCl, HOI, OH–
B. No catalyst, intermediates = H2O, HOCl, HOI, OH–
C. Catalyst = H2O, intermediates = HOCl, HOI, OH–
D. Catalyst = H2O, intermediate = HOCl, HOI
The reaction H2(g) + I2(g) → 2 HI(g) was thought to occur via a two-step mechanism:
Step 1: I2(g) ⇌ 2 I(g) (fast equilibrium)
Step 2: 2 I(g) + H2(g) → 2 HI(g) (slow)
Determine the rate law for the reaction.
Consider the reaction below:
A + C2 → AC2
The reaction is first-order in A and first-order in C2.
Two mechanisms are proposed for the reaction:
Mechanism 1 (single-step):
A + C2 → AC2
Mechanism 2:
B + C2 → BC + C slow
A + BC → AB + C fast
AB + 2 C → AC2 + B fast
Are both mechanisms valid? If yes why?
Consider this three-step mechanism for a reaction:
Cl2 (g) k1⇌k2 2 Cl (g) Fast
Cl (g) + CHCl3 (g) →k3 HCl (g) + CCl3 (g) Slow
Cl (g) + CCl3 (g) →k4 CCl4 (g) Fast
c. What is the predicted rate law?