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Triprotic Acids and Bases
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Problem 1
Problem 2
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Triprotic Acids and Bases
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17. Acid and Base Equilibrium / Triprotic Acids and Bases / Problem 2
Problem 2
Provide the K
a
expressions for the ionization of citric acid (H
3
C
6
H
5
O
7
).
A
K
a1
= [H
3
O
+
][H
2
O]/[H
3
C
6
H
5
O
7
][H
2
C
6
H
5
O
7
–
]K
a2
= [H
3
O
+
][H
2
O]/[H
2
C
6
H
5
O
7
–
][HC
6
H
5
O
7
2–
]K
a3
= [H
3
O
+
][H
2
O]/[HC
6
H
5
O
7
2–
][C
6
H
5
O
7
3–
]
B
K
a1
= [H
3
C
6
H
5
O
7
]/[H
2
C
6
H
5
O
7
–
][H
3
O
+
]K
a2
= [H
2
C
6
H
5
O
7
–
]/[HC
6
H
5
O
7
2–
][H
3
O
+
]K
a3
= [HC
6
H
5
O
7
2–
]/[C
6
H
5
O
7
3–
][H
3
O
+
]
C
K
a1
= [H
2
C
6
H
5
O
7
–
][H
3
O
+
]/[H
3
C
6
H
5
O
7
]K
a2
= [HC
6
H
5
O
7
2–
][H
3
O
+
]/[H
2
C
6
H
5
O
7
–
]K
a3
= [C
6
H
5
O
7
3–
][H
3
O
+
]/[HC
6
H
5
O
7
2–
]
D
K
a1
= [H
3
C
6
H
5
O
7
][H
2
C
6
H
5
O
7
–
]/[H
3
O
+
][H
2
O]K
a2
= [H
2
C
6
H
5
O
7
–
][HC
6
H
5
O
7
2–
]/[H
3
O
+
][H
2
O]K
a3
= [HC
6
H
5
O
7
2–
][C
6
H
5
O
7
3–
]/[H
3
O
+
][H
2
O]
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