Skip to main content
Back

General Chemistry Exam 1 Review Guide: Key Concepts and Study Notes

Study Guide - Smart Notes

Tailored notes based on your materials, expanded with key definitions, examples, and context.

Introduction to General Chemistry and Sustainable Chemistry

Green Chemistry and Its Importance

Green chemistry focuses on designing products and processes that minimize environmental impact and reduce the use of hazardous substances.

  • Green Chemistry Principles: Reduce waste, use renewable resources, and design safer chemicals.

  • Sustainable Chemistry: Integrates environmental, economic, and social considerations into chemical research and production.

  • Scientific Method: A systematic approach to research involving observation, hypothesis, experimentation, and conclusion.

  • Scientific Theory vs. Law: A theory explains why phenomena occur; a law describes consistent relationships under certain conditions.

Example: The development of biodegradable plastics using renewable resources is an application of green chemistry.

Atoms, Elements, and Atomic Theory

Structure of Atoms and Subatomic Particles

Atoms are composed of protons, neutrons, and electrons. The arrangement and number of these particles determine the properties of elements.

  • Protons: Positively charged particles in the nucleus.

  • Neutrons: Neutral particles in the nucleus.

  • Electrons: Negatively charged particles orbiting the nucleus.

  • Atomic Number (Z): Number of protons in an atom.

  • Mass Number (A): Total number of protons and neutrons.

Example: Carbon-12 has 6 protons, 6 neutrons, and 6 electrons.

Isotopes and Ions

  • Isotopes: Atoms of the same element with different numbers of neutrons.

  • Ions: Atoms or molecules that have gained or lost electrons, resulting in a net charge.

Example: Na+ is a sodium ion formed by losing one electron.

Chemical Reactions and Bonding

Chemical Bonds

Chemical bonds are forces that hold atoms together in compounds.

  • Ionic Bonds: Formed by the transfer of electrons from one atom to another.

  • Covalent Bonds: Formed by the sharing of electrons between atoms.

  • Metallic Bonds: Involve a 'sea' of delocalized electrons around metal ions.

Example: Sodium chloride (NaCl) is formed by the transfer of an electron from sodium to chlorine.

Periodic Table and Trends

The periodic table organizes elements by increasing atomic number and similar chemical properties.

  • Groups: Vertical columns with similar properties.

  • Periods: Horizontal rows indicating energy levels.

  • Trends: Atomic radius, ionization energy, and electronegativity change predictably across periods and groups.

Example: Alkali metals (Group 1) are highly reactive and have low ionization energies.

Chemical Quantities and Calculations

Mole Concept and Avogadro's Number

The mole is a fundamental unit for counting atoms, molecules, or ions in chemistry.

  • Avogadro's Number: particles per mole.

  • Molar Mass: The mass of one mole of a substance, expressed in grams per mole (g/mol).

Example: One mole of water (H2O) contains molecules and has a mass of 18.02 g.

Stoichiometry

Stoichiometry involves calculations based on balanced chemical equations to determine the quantities of reactants and products.

  • Balanced Equation: Ensures the same number of each atom on both sides of the reaction.

  • Limiting Reactant: The reactant that is completely consumed first, limiting the amount of product formed.

  • Theoretical Yield: Maximum amount of product that can be formed from given reactants.

  • Percent Yield:

States of Matter and Intermolecular Forces

Properties of Solids, Liquids, and Gases

The physical properties of matter depend on the arrangement and motion of particles.

  • Solids: Particles are closely packed in a fixed arrangement; definite shape and volume.

  • Liquids: Particles are close but can move past each other; definite volume, no definite shape.

  • Gases: Particles are far apart and move freely; no definite shape or volume.

Intermolecular Forces

  • Dipole-Dipole Forces: Attractions between polar molecules.

  • Dispersion (London) Forces: Weak attractions due to temporary dipoles in all molecules.

  • Hydrogen Bonds: Strong dipole-dipole attractions involving H bonded to N, O, or F.

Example: Water's high boiling point is due to hydrogen bonding.

Gas Laws

Ideal Gas Law

The ideal gas law relates the pressure, volume, temperature, and amount of a gas.

  • Equation:

  • P: Pressure (atm), V: Volume (L), n: Moles, R: Gas constant (0.0821 L·atm/mol·K), T: Temperature (K)

  • Given any three variables, the fourth can be calculated.

Example: Calculate the volume occupied by 2 moles of an ideal gas at 1 atm and 273 K.

Summary Table: Types of Intermolecular Forces

Type of Force

Occurs Between

Relative Strength

Example

Dipole-Dipole

Polar molecules

Moderate

HCl

Dispersion (London)

All molecules

Weakest

O2, N2

Hydrogen Bond

H with N, O, or F

Strongest

H2O, NH3

Additional info:

  • These notes are structured to cover the main learning outcomes for a General Chemistry exam, including atomic structure, chemical bonding, periodic trends, chemical calculations, states of matter, intermolecular forces, and gas laws.

  • Students should be familiar with using a calculator for stoichiometric and gas law calculations.

Pearson Logo

Study Prep