Domanda del libro di testo
Predict the product(s) that would result when molecules (a)–(p) are allowed to react under the following conditions: (ii) PBr₃ If no reaction occurs, write 'no reaction.'
(c)
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Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471
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TOC.tableOfContents
- Ch. 2 - General Chemistry Translated: Finding the Electrons114
- Ch. 3 - Alkanes and Cycloalkanes: Properties and Conformational Analysis109
- Ch. 4 - Acids and Bases/Electron Flow144
- Ch. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics118
- Ch. 6 - Stereoisomerism: Arrangement of Atoms in Space112
- Ch. 7 - Principles of Green (Organic) Chemistry3
- Ch. 8 - Alkenes 1: Properties and Electrophilic Additions158
- Ch. 9 - Alkenes 2: Oxidation and Reduction150
- Ch. 10 - Alkynes: Electrophilic Addition and Redox Reactions101
- Ch. 11 - Properties and Synthesis of Alkyl Halides: Radical Reactions108
- Ch. 12 - Substitution and Elimination: Reactions of Haloalkanes172
- Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination239
- Ch. 14 - Structural Identification 1: Infrared Spectroscopy and Mass Spectrometry54
- Ch. 15 - Structural Identification 2: Nuclear Magnetic Resonance Spectroscopy93
- Ch. 16 - Metals in Organic Chemistry48
- Ch. 17 - Carbonyl Addition Reactions: Aldehydes and Ketones45
- Ch. 18 - Nucleophilic Acyl Substitution 1: Carboxylic Acids18
- Ch. 19 - Nucleophilic Acyl Substitution 2: Carboxylic Acid Derivatives39
- Ch. 20 - Enolates: Carbonyl Addition and Substitution13
- Ch. 21 - Conjugated Systems 1: Stability and Addition Reactions56
- Ch. 22 - Conjugated Systems 2: Pericyclic Reactions54
- Ch. 23 - Benzene 1: Aromatic Stability and Substitution Reactions64
- Ch. 24 - Benzene 2: Reactions Influenced by the Aromatic Ring62
- Ch. 25 - Amines: Structure, Reactions, and Synthesis27
- Ch. 26 - Amino Acids, Proteins, and Peptide Synthesis9
- Ch. 27 - Carbohydrates, Nucleic Acids, and Lipids54
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Non è quello che usi tu?Cambia libro di testo
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Mullins 1st EditionCh. 13 - Alcohols, Ethers and Related Compounds: Substitution and EliminationProblema 106c(xi,xii)
Mullins 1st EditionCh. 13 - Alcohols, Ethers and Related Compounds: Substitution and EliminationProblema 106c(xi,xii)Capitolo 12, Problema 106c(xi,xii)
Predict the product(s) that would result when molecules (a)–(p) are allowed to react under the following conditions: (xi) HOCl, H₂O (xii) HIO₄ If no reaction occurs, write 'no reaction.'
(c) 
Guida verificata passo dopo passo1
Identify the functional groups present in the molecule. In this case, the molecule contains two alcohol groups (OH).
Consider the reaction conditions (xi) HOCl, H₂O. This is a hypochlorous acid in water, which can act as an oxidizing agent. It can convert alcohols to chlorohydrins.
For the reaction with HOCl, H₂O, the secondary alcohol group is more likely to react, forming a chlorohydrin by replacing the OH group with a Cl atom.
Consider the reaction conditions (xii) HIO₄. Periodic acid (HIO₄) is known to cleave vicinal diols (1,2-diols) into aldehydes or ketones.
For the reaction with HIO₄, the vicinal diol (the two adjacent OH groups) will be cleaved, resulting in the formation of two carbonyl compounds, typically ketones or aldehydes, depending on the structure of the original diol.
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Electrophilic Addition Reactions
Electrophilic addition reactions involve the addition of an electrophile to a nucleophile, typically occurring in alkenes and alkynes. In the context of HOCl and HIO₄, understanding how these reagents interact with double or triple bonds is crucial for predicting the products. The electrophile attacks the nucleophilic site, leading to the formation of new bonds and potentially rearranging the structure of the original molecule.
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05:39
Features of Addition Mechanisms.
Oxidation-Reduction Reactions
Oxidation-reduction (redox) reactions involve the transfer of electrons between species, resulting in changes in oxidation states. HIO₄ is a strong oxidizing agent that can cleave carbon-carbon bonds and oxidize alcohols to carbonyl compounds. Recognizing whether a reaction leads to oxidation or reduction is essential for predicting the final products of the reactions in question.
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00:54Distinguishing between Oxidation and Reduction
Functional Group Transformations
Functional group transformations refer to the chemical reactions that convert one functional group into another. In the reactions with HOCl and HIO₄, it is important to identify the functional groups present in the starting materials and how they may change during the reaction. This understanding helps in predicting the structure of the products formed after the reaction, including any potential rearrangements or eliminations.
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02:36Identifying Functional Groups
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Predict the product(s) that would result when molecules (a)–(p) are allowed to react under the following conditions: (i) SOCl₂ ; (ii) PBr₃ ; (iii) SOCl₂ , NEt₃ (iv) 1. TsCl, Et₃N 2. NaCN; (v) 1. TsCl, Et₃N 2. NaOt-Bu (vi) H₂SO₄ (vii) HCl; (viii) HBr; (ix) PCC; (x) H₂CrO₄ , H₂O (xi) HOCl, H₂O (xii) HIO₄ If no reaction occurs, write 'no reaction.'
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