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Ch.20 - Electrochemistry
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
20장, 문제 58

At 298 K a cell reaction has a standard cell potential of +0.17 V. The equilibrium constant for the reaction is 5.5 × 105. What is the value of n for the reaction?

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1
Identify the relationship between the standard cell potential (E°), the equilibrium constant (K), and the number of moles of electrons transferred (n) using the Nernst equation at equilibrium: E° = (RT/nF)ln(K).
Since the temperature is 298 K, use the simplified form of the Nernst equation: E° = (0.0257 V/n)ln(K).
Substitute the given values into the equation: 0.17 V = (0.0257 V/n)ln(5.5 × 10^5).
Solve for n by isolating it on one side of the equation: n = (0.0257 V/0.17 V)ln(5.5 × 10^5).
Calculate the natural logarithm of the equilibrium constant and then solve for n.

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이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
2m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Nernst Equation

The Nernst Equation relates the cell potential of an electrochemical reaction to the concentrations of the reactants and products. It is expressed as E = E° - (RT/nF)ln(Q), where E is the cell potential, E° is the standard cell potential, R is the universal gas constant, T is the temperature in Kelvin, n is the number of moles of electrons transferred, F is Faraday's constant, and Q is the reaction quotient.
추천 영상:
가이드 코스
01:17
The Nernst Equation

Standard Cell Potential (E°)

The standard cell potential (E°) is the voltage measured under standard conditions (1 M concentration, 1 atm pressure, and 25°C) for a galvanic cell. It indicates the tendency of a chemical reaction to occur spontaneously; a positive E° suggests a spontaneous reaction, while a negative E° indicates non-spontaneity.
추천 영상:
가이드 코스
01:27
Standard Cell Potential

Equilibrium Constant (K)

The equilibrium constant (K) quantifies the ratio of the concentrations of products to reactants at equilibrium for a reversible reaction. It is related to the standard cell potential through the equation ΔG° = -nFE°, where ΔG° is the change in Gibbs free energy. A larger K value indicates a greater tendency for the reaction to favor products at equilibrium.
추천 영상:
가이드 코스
01:14
Equilibrium Constant K