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문제 3a
Would you expect ∆S to be greater than, less than, or equal to zero in the following reactions?
a.
문제 3b
Would you expect ∆S to be greater than, less than, or equal to zero in the following reactions?
(b)
문제 4
Calculate Keq for the acid–base reaction shown. Which side is favored and why?
문제 5a
Calculate the oxidation numbers for the indicated atoms.
a.
문제 5b
Calculate the oxidation numbers for the indicated atoms.
b.
문제 5c
Calculate the oxidation numbers for the indicated atoms.
(c)
문제 5d
Calculate the oxidation numbers for the indicated atoms.
(d)
문제 5e
Calculate the oxidation numbers for the indicated atoms.
(e)
문제 16a
Predict the product of the following reactions.
(a)
문제 20a
The acid-catalyzed hydrolysis of an ester results in the formation of an equal amount of carboxylic acid and alcohol.
(a) Design a flow chart for separating the two products.
문제 20b
The acid-catalyzed hydrolysis of an ester results in the formation of an equal amount of carboxylic acid and alcohol.
(b) Once separated, how could you distinguish between the carboxylic acid and alcohol using IR spectroscopy?
문제 21
At the end of a reduction, there was found to be a small amount of unreacted amide along with the amine product dissolved in diethyl ether. How might you remove the amine from the ether?
문제 29
How would you reduce the alkene in the presence of a carboxylic acid?
문제 36
The absence of what band in the IR spectrum of the product in Figure 18.59 would be consistent with full conversion of the carboxylic acid to an acid chloride?
문제 49b
The following carboxylic acids were named incorrectly. Provide the correct name.
(b) 6-bromocyclohexane carboxylic acid
문제 59
When a chemist attempted the following reaction sequence, the desired product was not formed.
(a) Why?
(b) Suggest a solution to the problem. [Think about chemistry from the end of Chapter 13.]
문제 68
In Chapter 19, we will learn about the hydrolysis of t-butyl esters. In the reaction below, the hydrolysis is coupled to the decarboxylation reaction learned in this chapter. Suggest a mechanism for this reaction. [Hint: The formation of t-butanol proceeds by an SN1 reaction.]
문제 69
While acidic conditions were used in Assessment 18.68, decarboxylation of esters can also be conducted under basic conditions to give, at least temporarily, the enolate product shown. [We’ll learn more about the chemistry of enolates in Chapter 20.] Suggest a mechanism of this reaction. [Hint: The formation of chloromethane proceeds by an SN2 reaction.]
