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Malonic Ester Synthesis quiz #1 Flashcards

Malonic Ester Synthesis quiz #1
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  • What is the main difference between malonic ester synthesis and acetoacetic ester synthesis in terms of their products?
    The main difference is that malonic ester synthesis produces two carboxylic acids after hydrolysis, whereas acetoacetic ester synthesis produces only one carboxylic acid. This is because malonic ester starts with an extra OET group, leading to both groups being converted to carboxylic acids in the final step.
  • What structural feature distinguishes malonic ester from acetoacetic ester at the start of the synthesis?
    Malonic ester contains an extra OET (ethoxy) group compared to acetoacetic ester. This leads to both groups being converted to carboxylic acids after hydrolysis.
  • How do the reagents used in malonic ester synthesis compare to those in acetoacetic ester synthesis?
    The reagents used in malonic ester synthesis are identical to those used in acetoacetic ester synthesis. There is no change in the reagents between the two processes.
  • What happens to the OET groups in malonic ester during the hydrolysis step?
    During hydrolysis, both OET groups in malonic ester are converted into carboxylic acids. This results in a product with two carboxylic acid groups.
  • If you know acetoacetic ester synthesis, how can you quickly adapt to malonic ester synthesis?
    You can use the same reaction steps as acetoacetic ester synthesis and simply add carboxylic acids to the final product. The process is otherwise unchanged.
  • Why is it unnecessary to memorize a new set of reagents for malonic ester synthesis?
    It is unnecessary because the reagents are exactly the same as those used in acetoacetic ester synthesis. Only the final product differs due to the extra carboxylic acid group.
  • What is the outcome of hydrolyzing both ester groups in malonic ester?
    Hydrolyzing both ester groups in malonic ester yields two carboxylic acids. This is the key difference from acetoacetic ester synthesis.
  • How should you modify the product structure when switching from acetoacetic ester to malonic ester synthesis?
    You should add an extra carboxylic acid group to the product structure. This reflects the conversion of both ester groups during hydrolysis.
  • What advice is given to students who feel overwhelmed by the malonic ester synthesis chart?
    Students are advised not to worry because the reagents and steps are the same as acetoacetic ester synthesis. The only change is the addition of carboxylic acids in the final product.
  • What is the main teaching point emphasized about malonic ester synthesis in the video?
    The main point is that malonic ester synthesis is almost identical to acetoacetic ester synthesis except for the final product. The only difference is the presence of two carboxylic acids after hydrolysis.