Problema 73b
(b) If you take a 10.0-mL portion of the stock solution and dilute it to a total volume of 0.500 L, what will be the concentration of the final solution?
Problema 74a
(a) How many milliliters of a stock solution of 6.0 M HNO3 would you have to use to prepare 110 mL of 0.500 M HNO3?
Problema 74b
(b) If you dilute 10.0 mL of the stock solution to a final volume of 0.250 L, what will be the concentration of the diluted solution?
Problema 75
medical lab is testing a new anticancer drug on cancer cells. The drug stock solution concentration is 1.5 * 10-9 M, and 1.00 mL of this solution will be delivered to a dish containing 2.0 * 105 cancer cells in 5.00 mL of aqueous fluid. What is the ratio of drug molecules to the number of cancer cells in the dish?
Problema 76
Calicheamicin gamma-1, C55H74IN3O21S4, is one of the most potent antibiotics known: one molecule kills one bacterial cell. Describe how you would (carefully!) prepare 25.00 mL of an aqueous calicheamicin gamma-1 solution that could kill 1.0 * 108 bacteria, starting from a 5.00 * 10-9M stock solution of the antibiotic.
Problema 77
Pure acetic acid, known as glacial acetic acid, is a liquid with a density of 1.049 g/mL at 25 C. Calculate the molarity of a solution of acetic acid made by dissolving 20.00 mL of glacial acetic acid at 25 C in enough water to make 250.0 mL of solution.
- Glycerol, C3H8O3, is a substance used extensively in the manufacture of cosmetics, foodstuffs, antifreeze, and plastics. Glycerol is a water-soluble liquid with a density of 1.2656 g/mL at 15 °C. Calculate the molarity of a solution of glycerol made by dissolving 50.000 mL glycerol at 15 °C in enough water to make 250.00 mL of solution.
Problema 78
- You want to analyze a silver nitrate solution. What mass of KCl is needed to precipitate the silver ions from 15.0 mL of 0.200 M AgNO3 solution? (c) Given that a 0.150 M HCl(aq) solution costs $39.95 for 500 mL and that KCl costs $10/ton, which analysis procedure is more cost-effective?
Problema 79
Problema 81a
(a) What volume of 0.115 M HClO4 solution is needed to neutralize 50.00 mL of 0.0875 M NaOH?
Problema 81b
(b) What volume of HCl is needed to neutralize 2.87 g of Mg(OH)2?
Problema 81c
(c) If 25.8 mL of an AgNO3 solution is needed to precipitate all the Cl- ions in a 785-mg sample of KCl (forming AgCl), what is the molarity of the AgNO3 solution?
Problema 81d
(d) If 45.3 mL of a 0.108 M HCl solution is needed to neutralize a solution of KOH, how many grams of KOH must be present in the solution?
Problema 82a
(a) How many milliliters of 0.120 M HCl are needed to completely neutralize 50.0 mL of 0.101 M Ba(OH)2 solution?
Problema 82b
(b) How many milliliters of 0.125 M H2SO4 are needed to neutralize 0.200 g of NaOH?
Problema 82c
(c) If 55.8 mL of a BaCl2 solution is needed to precipitate all the sulfate ion in a 752-mg sample of Na2SO4, what is the molarity of the BaCl2 solution?
Problema 82d
(d) If 42.7 mL of 0.208 M HCl solution is needed to neutralize a solution of Ca(OH)2, how many grams of Ca(OH)2 must be in the solution?
- Some sulfuric acid is spilled on a lab bench. You can neutralize the acid by sprinkling sodium bicarbonate on it and then mopping up the resulting solution. The sodium bicarbonate reacts with sulfuric acid according to: 2 NaHCO3(s) + H2SO4(aq) → Na2SO4(aq) + 2 H2O(l) + 2 CO2(g). Sodium bicarbonate is added until the fizzing due to the formation of CO2(g) stops. If 27 mL of 6.0 M H2SO4 was spilled, what is the minimum mass of NaHCO3 that must be added to the spill to neutralize the acid?
Problema 83
Problema 84
The distinctive odor of vinegar is due to acetic acid, CH3COOH, which reacts with sodium hydroxide according to: CH3COOH1aq2 + NaOH1aq2¡ H2O1l2 + NaCH3COO1aq2 If 3.45 mL of vinegar needs 42.5 mL of 0.115 M NaOH to reach the equivalence point in a titration, how many grams of acetic acid are in a 1.00-qt sample of this vinegar?
Problema 85a
A 4.36-g sample of an unknown alkali metal hydroxide is dissolved in 100.0 mL of water. An acid–base indicator is added, and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 17.0 mL of the hydrochloric acid solution has been added. (a) What is the molar mass of the metal hydroxide?
Problema 85b
A 4.36-g sample of an unknown alkali metal hydroxide is dissolved in 100.0 mL of water. An acid–base indicator is added, and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 17.0 mL of the hydrochloric acid solution has been added. (b) What is the identity of the alkali metal cation: Li+, Na+, K+, Rb+, or Cs+?
Problema 86
An 8.65-g sample of an unknown group 2 metal hydroxide is dissolved in 85.0 mL of water. An acid–base indicator is added and the resulting solution is titrated with 2.50 M HCl(aq) solution. The indicator changes color, signaling that the equivalence point has been reached, after 56.9 mL of the hydrochloric acid solution has been added. (a) What is the molar mass of the metal hydroxide? (b) What is the identity of the metal cation: Ca2+, Sr2+, or Ba2+?
Problema 87a
A solution of 100.0 mL of 0.200 M KOH is mixed with a solution of 200.0 mL of 0.150 M NiSO4. (a) Write the balanced chemical equation for the reaction that occurs.
Problema 87b
A solution of 100.0 mL of 0.200 M KOH is mixed with a solution of 200.0 mL of 0.150 M NiSO4. (b) What precipitate forms?
Problema 87e
A solution of 100.0 mL of 0.200 M KOH is mixed with a solution of 200.0 mL of 0.150 M NiSO4. (e) What is the concentration of each ion that remains in solution?
Problema 88b
A solution is made by mixing 1.5 g of LiOH and 23.5 mL of 1.000 M HNO3. (b) Calculate the concentration of each ion remaining in solution.
Problema 88c
A solution is made by mixing 1.5 g of Sr(OH)2 and 23.5 mL of 1.000 M HNO3. (c) Is the resulting solution acidic or basic?
Problema 89
A 0.5895-g sample of impure magnesium hydroxide is dissolved in 100.0 mL of 0.2050 M HCl solution. The excess acid then needs 19.85 mL of 0.1020 M NaOH for neutralization. Calculate the percentage by mass of magnesium hydroxide in the sample, assuming that it is the only substance reacting with the HCl solution.
Problema 90
A 1.248-g sample of limestone rock is pulverized and then treated with 30.00 mL of 1.035 M HCl solution. The excess acid then requires 11.56 mL of 1.010 M NaOH for neutralization. Calculate the percentage by mass of calcium carbonate in the rock, assuming that it is the only substance reacting with the HCl solution.
Problema 91a,b
Uranium hexafluoride, UF6, is processed to produce fuel for nuclear reactors and nuclear weapons. UF6 can be produced in a two-step reaction. Solid uranium (IV) oxide, UO2, is first made to react with hydrofluoric acid (HF) solution to form solid UF4 with water as a by-product. UF4 further reacts with fluorine gas to form UF6. (a) Write the balanced molecular equations for the conversion of UO2 into UF4 and the conversion of UF4 to UF6. (b) Which step is an acid-base reaction?
Problema 92b
The accompanying photo shows the reaction between a solution of Cd(NO3)2 and one of Na2S. (b) What ions remain in solution?
Ch.4 - Reactions in Aqueous Solution
