문제 43b
Suggest an appropriate base to synthesize the alkene as the major product from the starting haloalkane.
(b)
문제 44a
Paying close attention to the stereochemical outcome, predict the product of these elimination reactions.
(a)
문제 44c
Paying close attention to the stereochemical outcome, predict the product of these elimination reactions.
(c)
문제 44d
Paying close attention to the stereochemical outcome, predict the product of these elimination reactions.
(d)
문제 45
The cis-diastereomer undergoes E2 elimination 500 times faster than the trans form. Explain.
문제 46a
Provide a mechanism for the following E1 reactions.
(a)
문제 46b
Provide a mechanism for the following E1 reactions.
(b)
문제 46c
Provide a mechanism for the following E1 reactions.
(c)
문제 47a
Predict the product of the following rearrangement-prone E1 eliminations.
(a)
문제 47b
Predict the product of the following rearrangement-prone E1 eliminations.
(b)
문제 47c
Predict the product of the following rearrangement-prone E1 eliminations.
(c)
문제 48
Which reaction, E2 or Sₙ2, would you expect to be more favorable at higher temperatures?
문제 49b
For the following reactions we have not seen yet, which side, if either, would be favored by increasing the temperature?
(b)
문제 49c
For the following reactions we have not seen yet, which side, if either, would be favored by increasing the temperature?
(c)
문제 49d
For the following reactions we have not seen yet, which side, if either, would be favored by increasing the temperature?
(d)
문제 50a
For which of the following reactions would you expect elimination to be more favored than substitution?
(a)
문제 50b
For which of the following reactions would you expect elimination to be more favored than substitution?
(b)
문제 50c
For which of the following reactions would you expect elimination to be more favored than substitution?
(c)
문제 50d
For which of the following reactions would you expect elimination to be more favored than substitution?
(d)
문제 50e
For which of the following reactions would you expect elimination to be more favored than substitution?
(e)
문제 50f
For which of the following reactions would you expect elimination to be more favored than substitution?
(f)
문제 51b
Predict the product of the following reactions.
(b)
문제 51d
Predict the product of the following reactions.
(d)
문제 51e
Predict the product of the following reactions.
(e)
문제 51f
Predict the product of the following reactions.
(f)
문제 52b
Suggest a mechanism for the following substitution reactions.
(b)
문제 52c
Suggest a mechanism for the following substitution reactions.
(c)
문제 52d
Suggest a mechanism for the following substitution reactions.
(d)
문제 53a
Suggest a mechanism for the following elimination reactions.
(a)
문제 53c
Suggest a mechanism for the following elimination reactions.
(c)
Ch. 12 - Substitution and Elimination: Reactions of Haloalkanes
