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문제 48a
Draw a structure for each of the following:
a. N,N-dimethylhexanamide
문제 48b
Draw a structure for each of the following:
b. 3,3-dimethylhexanamide
문제 48c,k
Draw a structure for each of the following:
c. cyclohexanecarbonyl chloride
k. benzoyl chloride
문제 48d
Draw a structure for each of the following:
d. propanenitrile
문제 48g
Draw a structure for each of the following:
g. benzoic anhydride
문제 48i
Draw a structure for each of the following:
i. 3-methylbutanenitrile
문제 48j
Draw a structure for each of the following:
j. cycloheptanecarboxylic acid
문제 49a
Name the following:
a.
문제 49c
Name the following:
c.
문제 49e
Name the following:
e.
문제 49f
Name the following:
f.
문제 50a,b
What compounds are formed from the reaction of benzoyl chloride with the following reagents?
a. sodium acetate
b. water
문제 50e
What compounds are formed from the reaction of benzoyl chloride with the following reagents?
e. aqueous NaOH
문제 50f
What compounds are formed from the reaction of benzoyl chloride with the following reagents?
f. cyclohexanol
문제 50g,h
What compounds are formed from the reaction of benzoyl chloride with the following reagents?
g. excess benzylamine
h. 4-chlorophenol
문제 50i
What compounds are formed from the reaction of benzoyl chloride with the following reagents?
i. isopropyl alcohol
문제 50k
What compounds are formed from the reaction of benzoyl chloride with the following reagents?
k. potassium formate
문제 51c
What compounds are obtained from the following hydrolysis reactions?
c.
문제 51d
What compounds are obtained from the following hydrolysis reactions?
d.
문제 53
Because bromocyclohexane is a secondary alkyl halide, both cyclohexanol and cyclohexene are formed when the alkyl halide reacts with hydroxide ion. Suggest a method to synthesize cyclohexanol from bromocyclohexane that forms little or no cyclohexene.
문제 54
a. Which compound would you expect to have a greater dipole moment, methyl acetate or butanone?
b. Which would you expect to have a higher boiling point?
문제 57d
Using an alcohol for one method and an alkyl halide for the other, show two ways to make each of the following esters:
d. methyl phenylethanoate (odor of honey)
문제 58a,b
What reagents would you use to convert methyl propanoate to the following compounds?
a. isopropyl propanoate
b. sodium propanoate
문제 58c,d
What reagents would you use to convert methyl propanoate to the following compounds?
c. N-ethylpropanamide
d. propanoic acid
문제 59a
What products would you expect to obtain from the following reactions?
a. malonic acid + 2 acetyl chloride
문제 59b
What products would you expect to obtain from the following reactions?
b. methyl carbamate + methylamine
문제 59c,d
What products would you expect to obtain from the following reactions?
c. urea + water
d. β-ethylglutaric acid + acetyl chloride + Δ
문제 60
A compound with molecular formula C5H10O2 gives the following IR spectrum. When it undergoes acid-catalyzed hydrolysis, the compound with the 1H NMR spectrum shown below is formed. Identify the compounds.
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문제 61
Aspartame, the sweetener used in the commercial products NutraSweet and Equal, is 200 times sweeter than sucrose. What products will be obtained if aspartame is hydrolyzed completely in an aqueous solution of HCl?
문제 63(5)
a. Which of the following reactions does not give the carbonyl product shown?
b. Which of the reactions that do not occur can be made to occur if an acid catalyst is added to the reaction mixture?
5.
