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Ch 41: Atomic Physics
Knight Calc - Physics for Scientists and Engineers 5th Edition
Knight Calc5th EditionPhysics for Scientists and EngineersISBN: 9780137344796당신이 사용하는 게 아니라요?교과서 변경
41장, 문제 31

For an electron in the 1s state of hydrogen, what is the probability of being in a spherical shell of thickness 0.010aB at distance (a) ½ aB, (b) aB, and (c) 2aB from the proton?

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Understand the problem: The probability of finding an electron in a spherical shell is determined by the radial probability density function, which is derived from the square of the radial wavefunction multiplied by the volume element. For the hydrogen atom in the 1s state, the radial wavefunction is given by \( R_{1s}(r) = \frac{2}{a_B^{3/2}} e^{-r/a_B} \), where \( a_B \) is the Bohr radius.
Write the expression for the radial probability density: The radial probability density is \( P(r) = |R_{1s}(r)|^2 \cdot 4\pi r^2 \), where \( |R_{1s}(r)|^2 \) is the square of the radial wavefunction. Substituting \( R_{1s}(r) \), we get \( P(r) = \frac{4}{a_B^3} e^{-2r/a_B} \cdot 4\pi r^2 \).
Set up the probability for a spherical shell: The probability of finding the electron in a thin spherical shell of thickness \( dr \) at a distance \( r \) is \( dP = P(r) \cdot dr \). Substituting \( P(r) \), we have \( dP = \frac{16\pi}{a_B^3} r^2 e^{-2r/a_B} dr \).
Evaluate the probability for each case: For each distance \( r \) (\( r = \frac{1}{2}a_B, a_B, 2a_B \)), substitute the value of \( r \) into the expression \( dP = \frac{16\pi}{a_B^3} r^2 e^{-2r/a_B} dr \) and use \( dr = 0.010a_B \) to calculate the probability for the corresponding spherical shell.
Perform the calculations: For each case, simplify the expression by substituting \( r \) and \( dr \) into \( dP \). This will yield the probability for the electron to be in the specified spherical shell at the given distance. Note that the final numerical evaluation can be done separately if needed.

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주요 개념

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Probability density in quantum mechanics refers to the likelihood of finding a particle, such as an electron, in a specific region of space. For the hydrogen atom, the probability density is derived from the square of the wave function's amplitude, and it is crucial for calculating the probability of the electron being found within a given spherical shell at various distances from the nucleus.
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