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HOMO LUMO
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Problem 3
HOMO LUMO
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16. Conjugated Systems / HOMO LUMO / Problem 3
Problem 3
Determine the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) for the given allylic cation and allylic anion.
A
HOMO: Allylic cation:
Ψ
2
; Allylic anion:
Ψ
1
LUMO: Allylic cation: Ψ
1
; Allylic anion:
Ψ
3
B
HOMO: Allylic cation:
Ψ
1
; Allylic anion:
Ψ
2
LUMO: Allylic cation:
Ψ
2
; Allylic anion:
Ψ
3
C
HOMO: Allylic cation:
Ψ
2
; Allylic anion:
Ψ
3
LUMO: Allylic cation:
Ψ
1
; Allylic anion:
Ψ
2
D
HOMO: Allylic cation:
Ψ
3
; Allylic anion:
Ψ
2
LUMO: Allylic cation:
Ψ
2
; Allylic anion:
Ψ
1
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