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Radical Stability
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Radical Stability
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11. Radical Reactions / Radical Stability / Problem 2
Problem 2
Rationalize the ranking of the following ethers according to their ability to form explosive peroxides.
A
Ether (a) has the most hindered oxygen
Ether(b) has a less hindered oxygen
Ether (c) has the least hindered oxygen
Ether (d) lacks any hydrogen at the α-carbons
B
Ether (a) forms the most stable radical
Ether(b) forms a less stable radical
Ether (c) forms the least stable radical
The lone pairs of oxygen in ether (d) are in conjugation with the phenyl groups
C
Ether (a) forms the most stable radical
Ether(b) forms a less stable radical
Ether (c) forms the least stable radical
Ether (d) lacks any hydrogen at the α-carbons
D
None of these
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