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Chapter 8: Reactions of Alkenes – Mechanisms, Stereochemistry, and Applications

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Addition Reaction

  • Provide the mechanism
    01:15
  • Features of Addition Mechanisms.
    05:39

Markovnikov

  • Provide the mechanism
    01:26
  • How to add to asymmetrical double bonds.
    03:38

Free Radical Halogenation

  • The one reaction that alkanes will actually undergo.
    02:05
  • Explaining the following problem.
    00:34
  • Show the entire chain reaction mechanism.
    04:08

Hydroboration

  • General properties of hydroboration-oxidation.
    06:38
  • Acid-catalyzed hydroboration-oxidation mechanism
    06:14

Oxymercuration

  • Acid-catalyzed oxymercuration-reduction mechanism
    09:01
  • General properties of oxymercuration-reduction.
    05:

Halogenation

  • Halogenation Mechanism
    03:45
  • General properties of halogenation.
    02:27

Halohydrin

  • Halohydrin Mechanism
    04:48
  • General properties of halohydrin formation.
    01:44

Epoxidation

  • Halohydrins to epoxides via intramolecular SN2.
    02:26
  • General properties of epoxidation.
    02:19
  • The mechanism of how peroxy acids make epoxides.
    03:19

Dihydroxylation

  • General properties of syn vicinal dihydroxylation.
    03:50
  • Predict the product for the following multi-step reaction.
    04:42

Ozonolysis

  • General properties of ozonolysis.
    06:30

Alkene Metathesis

  • Guided course
    Alkene Metathesis Example 1
    1:47
  • Guided course
    Alkene Metathesis Example 4
    1:41
  • Guided course
    Alkene Metathesis Example 2
    3:04

Carbene

  • Reaction with a simple carbene.
    01:48
  • Reaction with diazomethane and light or heat.
    03:01
  • Reaction with chloroform (CHCl3) and tert-butoxide.
    03:04