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Ch 18: A Macroscopic Description of Matter
Chapter 18, Problem 66a

Five grams of nitrogen gas at an initial pressure of 3.0 atm and at 20°C undergo an isobaric expansion until the volume has tripled. What is the gas volume after the expansion?

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Step 1: Start by identifying the given values. The mass of nitrogen gas is 5 grams, the initial pressure \( P_1 \) is 3.0 atm, the initial temperature \( T_1 \) is 20°C (convert this to Kelvin: \( T_1 = 20 + 273.15 = 293.15 \ \text{K} \)), and the volume triples during the isobaric process.
Step 2: Use the molar mass of nitrogen gas (\( N_2 \)) to calculate the number of moles \( n \). The molar mass of \( N_2 \) is approximately 28.02 g/mol. Use the formula \( n = \frac{m}{M} \), where \( m \) is the mass and \( M \) is the molar mass.
Step 3: Apply the ideal gas law \( PV = nRT \) to find the initial volume \( V_1 \). Rearrange the equation to solve for \( V_1 \): \( V_1 = \frac{nRT_1}{P_1} \), where \( R \) is the ideal gas constant (0.0821 L·atm/(mol·K)). Substitute the known values for \( n \), \( R \), \( T_1 \), and \( P_1 \).
Step 4: Since the process is isobaric (constant pressure), the volume triples. Therefore, the final volume \( V_2 \) is related to the initial volume \( V_1 \) by \( V_2 = 3V_1 \). Use this relationship to calculate \( V_2 \).
Step 5: Substitute the value of \( V_1 \) obtained in Step 3 into the equation \( V_2 = 3V_1 \) to determine the final volume after the expansion. Ensure the units are consistent throughout the calculation.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law is fundamental in understanding gas behavior under various conditions, allowing us to predict how changes in one variable affect the others.
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Ideal Gases and the Ideal Gas Law

Isobaric Process

An isobaric process is a thermodynamic process in which the pressure remains constant. During this type of expansion, the volume of the gas changes while the pressure does not, which is crucial for calculating the final volume when the initial conditions are known.
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Volume Calculation

To find the final volume of a gas after an isobaric expansion, we can use the relationship between initial and final volumes, given that the pressure is constant. In this case, if the volume triples, the final volume can be calculated by multiplying the initial volume by three, which is essential for solving the problem.
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Related Practice
Textbook Question

In Problems 67,68,69,67, 68, 69, and 7070 you are given the equation(s) used to solve a problem. For each of these, you are to draw a pV diagram.

(T2+273) K=200 kPa500 kPa×1×(400+273) K(T_2 + 273) \text{ K} = \frac{200 \text{ kPa}}{500 \text{ kPa}} \times 1 \times (400 + 273) \text{ K}

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Textbook Question

10 g of dry ice (solid CO₂) is placed in a 10,000 cm3 container, then all the air is quickly pumped out and the container sealed. The container is warmed to 0°C, a temperature at which CO₂ is a gas. What is the gas pressure? Give your answer in atm. The gas then undergoes an isothermal compression until the pressure is 3.0 atm, immediately followed by an isobaric compression until the volume is 1000 cm3.

922
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Textbook Question

A container of gas at 2.0 atm pressure and 127°C is compressed at constant temperature until the volume is halved. It is then further compressed at constant pressure until the volume is halved again. Show this process on a pV diagram.

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Textbook Question

Five grams of nitrogen gas at an initial pressure of 3.0 atm and at 20°C undergo an isobaric expansion until the volume has tripled. What is the gas temperature after the expansion (in °C)? The gas pressure is then decreased at constant volume until the original temperature is reached.

619
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Textbook Question

In Problems 67,68,69,67, 68, 69, and 7070 you are given the equation(s) used to solve a problem. For each of these, you are to write a realistic problem for which this is the correct equation(s).

p2=300 cm3100 cm3×1×2 atmp_2 = \frac{300 \text{ cm}^3}{100 \text{ cm}^3} \times 1 \times 2 \text{ atm}

882
views
Textbook Question

In Problems 67,68,69,67, 68, 69, and 7070 you are given the equation(s) used to solve a problem. For each of these, you are to write a realistic problem for which this is the correct equation(s).

(T2+273) K=200 kPa500 kPa×1×(400+273) K(T_2 + 273) \text{ K} = \frac{200 \text{ kPa}}{500 \text{ kPa}} \times 1 \times (400 + 273) \text{ K}

642
views