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Which statements explains the energy requirements of chemical reactions?
A) The rate of reaction increases with both increasing temperature and activation energy.
B) The rate of reaction increases with increasing temperature and decreasing activation energy.
C) The rate of reaction increases with decreasing temperature and increasing activation energy.
D) The rate of reaction increases with both decreasing temperature and activation energy.
Which of the following describes the reaction in the energy diagram below?
True or False. Although a catalyst does take part in the reaction, it is not consumed since it reacts in one step and is then regenerated in the next step.
Describe what happens to the rate of the reaction of H2 and Cl2 in a cylinder with a movable piston when a catalyst is added.
H2 (g) + Cl2 (g) → 2 HCl (g)
The following reaction was studied in an experiment: Ag+(aq) + Cl−(aq) → AgCl(s), and the data are listed below. Calculate the average rate of the reaction for the time interval 120s to 180s.
The balanced equation for the reaction of sodium sulfide with hydrogen bromide is as follows.
2 HBr(aq) + Na2S(aq) → H2S(g) + 2 NaBr(aq)
What is the value of Δ[H2S]/Δt if Δ[HBr]/Δt = 2.8×10—3 M/s during the same time period?
Estimate the instantaneous rate of formation of O2 at 70 s for the reaction based on the given graph.
2 N2O5 → 4 NO2 + O2
How does the rate constant change with increasing activation energy?
The rate constant values for a hypothetical reaction are 1.250×10−4 s−1 and 8.764×10−3 s−1 at 345 K and 360 K, respectively. Calculate the value of activation energy.
The decomposition of nitramide (O2NNH2) is being studied where the concentration–time data for nitramide (O2NNH2) and H+ were gathered. Nitramide decomposes into nitrous oxide (N2O) gas and water. What is the balanced reaction equation?
Identify the rate law for the theoretical three-step mechanism below:
A2 ↔ A Fast
A + CB → C + BA Slow
A + BA → BA2 Fast
The following data were gathered for the reaction
CD → C + D
Time(s) [CD] (M)
0 1.00
10 0.833
20 0.714
30 0.625
40 0.555
50 0.505
60 0.455
Determine the following:
a. Order of the reaction
b. Rate constant of the reaction
c. Concentration of CD at 80 s
The components of a reaction after 0 mins and 20 mins are shown below.
After 7 half-life periods, what fraction of reactant is still present if the reaction is first-order?
A hypothetical reversible reaction M → N is represented by the following five figures. Blue spheres represent M while yellow spheres represent N. The progress of the reaction is depicted by the figures from left to right. Does the reaction reach equilibrium in any of the figures? If so, which figure(s) show the system in equilibrium?
The equilibrium constant for the following decomposition reaction at 75.0 °C is 2.73.
NH3BF3(s) ⇌ NH3(g) + BF3(g)
What is the minimum amount of NH3BF3(s) in grams that has to be added to a 0.350 L flask in order to reach equilibrium?
Calculate Kc for each reaction. b. CH4(g) + H2O(g) ⇌ CO(g) + 3 H2(g), Kp = 2.5 x 103 (at 1200 K)
At 298 K, the Kc for the reaction 2 H2S(g) ⇋ 2 H2(g) + S2(g) is 1.67×10−7. What is the Kc for the reaction H2S(g) ⇋ H2(g) + 1/2 S2(g) at the same temperature?
Consider the hypothetical reaction P2 + Q2 ⇌ 2 PQ. Provided in the table below are the rate constants of the forward and reverse reactions at different temperatures.
Determine if the reaction is endothermic or exothermic and justify your answer.
A reaction vessel at 27 °C contains a mixture of SO2 (P = 3.00 atm) and O2 (P = 1.00 atm). When a catalyst is added, this reaction takes place: 2 SO2(g) + O2(g) ⇌ 2 SO3(g). At equilibrium, the total pressure is 3.75 atm. Find the value of Kc.
Consider the reaction for the dissolution of Barium carbonate:
BaCO3(s) ⇌ Ba2+(aq) + CO32-(aq) Kc = 8.10 x 10-8 at 25°C
Identify if additional solid barium carbonate is dissolved if it was added to a solution 2.0-L solution that already contains 15.02 g BaCO3.