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The concentration of FeCl2 in an aqueous solution was determined by redox titration with K2Cr2O7. The sample was first dissolved in HCl to make the solution acidic. The working reaction is shown below:
Cr2O72–(aq) + 6 Fe2+(aq) + 14 H+(aq) → 2 Cr3+(aq) + 6 Fe3+(aq) + 7 H2O(l)
In the diagram below, theCr2O72– ions are depicted in green spheres and Fe2+ ions are depicted in orange spheres. In the buret, the concentration of Cr2O72– ions is 0.170 M. The volumes in the buret and the flask are the same. Calculate the concentration of the FeCl2 in the solution and determine the percentage of the Cr2O72– that must be added in order to react with all the Fe2+ ions.
A student accidentally spills 600 mL of 0.300 M HCl solution on a table. Calculate the mass of Na2CO3 required to completely neutralize the acid. The neutralization reaction is 2 HCl(aq) + Na2CO3(aq) → 2 NaCl(aq) + CO2(g) + H2O(l).
The amount of iron in ore was determined using dichrometry wherein dichromate (Cr2O72–) is used to oxidize Fe2+ to Fe3+. The net ionic equation is as follows:
Cr2O72–(aq) + 6 Fe2+(aq) + 14 H+(aq) → 6 Fe3+(aq) + 2 Cr3+(aq) + 7 H2O(l)
Calculate the mass percent of iron in a 0.2485 g sample of ore given that 21.41 mL of 0.0167 M Cr2O72– was used to titrate all of the Fe2+.
The balanced equation for the reaction of bromine, Br2, with aqueous thiosulfate in neutral solution is Br2(l) + 2 S2O32−(aq) → S4O62−(aq) + 2 I−(aq). How much Br2 in grams is in a solution if 37.20 mL of 0.175 M Na2S2O3 is needed to titrate the Br2 solution?
Calculate the volume of 0.115 M K2O solution needed to react with 150 mL of 0.200 M Ni(NO3)2 based on the reaction below:
K2O(aq) + Ni(NO3)2(aq) → 2 KNO3(aq) + NiO(s)
Lead (ll) nitrate and ammonium iodide react to form lead(lI) iodide and ammonium nitrate according to the following reaction:
Pb(NO3)2 (aq) + 2 NH4I (aq) → PbI2 (s) + 2 NH4NO3 (aq)
How many mL of a 0.178 M ammonium iodide solution is required to react with 232 mL of a 0.355 M Lead (ll) nitrate solution? And how many moles of lead(lI) iodide are formed from this reaction?
The reaction of WCl6 with Al at 400 °C produces black crystals of a compound containing only tungsten and chlorine. When this compound is reduced with hydrogen, it gives 0.8916 g of tungsten metal and hydrochloric acid, which is absorbed in water. Titration of the hydrochloric acid requires 92.4 mL of 0.2102 M NaOH to reach the end point. What is the empirical formula of the black tungsten chloride?