Crystal Field Theory: Tetrahedral Complexes definitions Flashcards
Crystal Field Theory: Tetrahedral Complexes definitions
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Tetrahedral ComplexA molecular structure where four ligands are symmetrically arranged around a central atom.LigandAn ion or molecule that binds to a central metal atom to form a coordination complex.d OrbitalA type of atomic orbital with specific shapes and orientations, crucial in transition metal chemistry.dxy OrbitalA d orbital oriented between the x and y axes, experiencing strong ligand interactions.dyz OrbitalA d orbital oriented between the y and z axes, experiencing strong ligand interactions.dxz OrbitalA d orbital oriented between the x and z axes, experiencing strong ligand interactions.dx2-y2 OrbitalA d orbital oriented along the x and y axes, experiencing weaker ligand interactions.dz2 OrbitalA d orbital oriented along the z axis, experiencing weaker ligand interactions.Triplet SetA group of three orbitals with the highest energy in a tetrahedral complex.Pair SetA group of two orbitals with lower energy in a tetrahedral complex.Crystal Field SplittingThe energy difference between sets of d orbitals in a coordination complex.DeltaThe symbol representing the energy difference between d orbital sets in a complex.Octahedral ComplexA molecular structure where six ligands are symmetrically arranged around a central atom.Square Planar ComplexA molecular structure where four ligands are arranged in a square around a central atom.Crystal Field DiagramA visual representation of the energy levels of d orbitals in a coordination complex.