Bruice 8th Edition
Ch. 16 - Reactions of Aldehydes and Ketones • More Reactions of Carboxylic Acid DerivativesProblema 65a
Identify A through O:
Problema 65b
Identify A through O:
Problema 65c
Identify A through O:
Problema 65d
Identify A through O:
Problema 65e
Identify A through O:
Problema 65f
Identify A through O:
Problema 65g
Identify A through O:
Problema 65h
Identify A through O:
Problema 66e,f
What are the products of the following reactions?
e.
f.
Problema 66i
What are the products of the following reactions?
i.
Problema 66j
What are the products of the following reactions?
j.
Problema 67
The only organic compound obtained when compound Z undergoes the following sequence of reactions gives the 1H NMR spectrum shown. Identify compound Z.
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Problema 68a
Propose a mechanism for each of the following reactions:
a.
Problema 68b
Propose a mechanism for each of the following reactions:
b.
Problema 69
How many signals would the product of the following reaction show in
a. its 1H NMR spectrum?
b. its 13C NMR spectrum?
Problema 70
Fill in the boxes with the appropriate reagents:
Problema 71
Rank the following compounds from most reactive to least reactive toward nucleophilic addition:
Problema 72a
How could you convert N-methylbenzamide to the following compounds?
a. N-methylbenzylamine
Problema 72b
How could you convert N-methylbenzamide to the following compounds?
b. benzoic acid
Problema 72c
How could you convert N-methylbenzamide to the following compounds?
c. methyl benzoate
Problema 72d
How could you convert N-methylbenzamide to the following compounds?
d. benzyl alcohol
Problema 73c,d
What are the products of the following reactions? Show all stereoisomers that are formed.
c.
d.
Problema 74a
List three different sets of reagents (each set consisting of a carbonyl compound and a Grignard reagent) that could be used to prepare each of the following tertiary alcohols:
a.
Problema 74b
List three different sets of reagents (each set consisting of a carbonyl compound and a Grignard reagent) that could be used to prepare each of the following tertiary alcohols:
b.
Problema 75a,b
What product is formed when 3-methyl-2-cyclohexenone reacts with each of the following reagents?
a. CH3MgBr followed by H3O+
b. (CH3CH2)2CuLi followed by H3O+
Problema 75c,d
What product is formed when 3-methyl-2-cyclohexenone reacts with each of the following reagents?
c. HBr
d. CH3CH2SH
Problema 77c,d
What is the product of each of the following reactions?
c.
d.
Problema 78a
Propose a mechanism for each of the following reactions:
a.
Problema 78b
Propose a mechanism for each of the following reactions:
b.
Problema 79b
Draw structures for A-D for each of the following:
b.