Problema 37
What are the units of k for each type of reaction?
a. first-order reaction
b. second-order reaction
c. zero-order reaction
Problema 38a
This reaction is first order in N2O5: N2O5(g) → NO3(g) + NO2(g) The rate constant for the reaction at a certain temperature is 0.053/s. a. Calculate the rate of the reaction when [N2O5] = 0.055 M
Problema 38b
This reaction is first order in N2O5: N2O5(g) → NO3(g) + NO2(g) The rate constant for the reaction at a certain temperature is 0.053/s. b. What would the rate of the reaction be at the concentration indicated in part a if the reaction were second order? Zero order? (Assume the same numerical value for the rate constant with the appropriate units.)
Problema 39a
A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C.
a. Write a rate law for the reaction.
Problema 39b
A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C. b. What is the overall order of the reaction?
Problema 39c,d,e,f
A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C c. By what factor does the reaction rate change if [A] is doubled (and the other reactant concentrations are held constant)? d. By what factor does the reaction rate change if [B] is doubled (and the other reactant concentrations are held constant)? e. By what factor does the reaction rate change if [C] is doubled? f. By what factor does the reaction rate change if the concentrations of all three reactants are doubled?
Problema 40a
A reaction in which A, B, and C react to form products is zero order in A, one-half order in B, and second order in C. a. Write a rate law for the reaction.
Problema 40b
A reaction in which A, B, and C react to form products is zero order in A, one-half order in B, and second order in C. b. What is the overall order of the reaction? order in A, one-half order in B, and second order in C
Problema 40c,d,e,f
A reaction in which A, B, and C react to form products is zero order in A, one-half order in B, and second order in C. c. By what factor does the reaction rate change if [A] is doubled (and the other reactant concentrations are held constant)? d. By what factor does the reaction rate change if [B] is doubled? e. By what factor does the reaction rate change if [C] is doubled? f. By what factor does the reaction rate change if [C] is doubled (and the other reactant concentrations are held constant)?
- Consider the data showing the initial rate of a reaction (A → products) at several different concentrations of A. What is the order of the reaction? Write a rate law for the reaction including the value of the rate constant, k.
Problema 41
- Consider the tabulated data showing the initial rate of a reaction (A → products) at several different concentrations of A. What is the order of the reaction? Write a rate law for the reaction including the value of the rate constant, k.
Problema 43
Problema 44
Consider the tabulated data showing the initial rate of a reaction (A → products) at several different concentrations of A. What is the order of the reaction? Write a rate law for the reaction including the value of the rate constant, k.
- The tabulated data were collected for this reaction: 2 NO2(g) + F2(g) → 2 NO2F(g). Write an expression for the reaction rate law and calculate the value of the rate constant, k. What is the overall order of the reaction?
Problema 45
Problema 46
The tabulated data were collected for this reaction: CH3Cl(g) + 3 Cl2(g) → CCl4( g) + 3 HCl(g)

Write an expression for the reaction rate law and calculate the value of the rate constant, k. What is the overall order of the reaction?
Problema 47
Indicate the order of reaction consistent with each observation. a. A plot of the concentration of the reactant versus time yields a straight line. Indicate the order of reaction consistent with each observation b. The reaction has a half-life that is independent of initial concentration. c. A plot of the inverse of the concentration versus time yields a straight line.
Problema 48a,b
Indicate the order of reaction consistent with each observation.
a. The half-life of the reaction gets shorter as the initial concentration is increased.
b. A plot of the natural log of the concentration of the reactant versus time yields a straight line.
Problema 48c
Indicate the order of reaction consistent with each observation c. The half-life of the reaction gets longer as the initial concentration is increased.
Problema 49
The tabulated data show the concentration of AB versus time for this reaction: AB( g)¡A( g) + B( g) Time (s) [AB] (M) 0 0.950 50 0.459 100 0.302 150 0.225 200 0.180 250 0.149 300 0.128 350 0.112 400 0.0994 450 0.0894 500 0.0812 Determine the order of the reaction and the value of the rate constant. Predict the concentration of AB at 25 s.
- The tabulated data show the concentration of cyclobutane (C4H8) versus time for this reaction: C4H8 -> 2 C2H4. Time (s) [C4H8] (M) 0 1.000 10 0.894 20 0.799 30 0.714 40 0.638 50 0.571 60 0.510 70 0.456 80 0.408 90 0.364 100 0.326. Determine the order of the reaction and the value of the rate constant. What is the rate of reaction when [C4H8] = 0.25 M?
Problema 51
Problema 52
The reaction A¡products was monitored as a function of time. The results are shown here. Time (s) [A] (M) 0 1.000 25 0.914 50 0.829 75 0.744 100 0.659 125 0.573 150 0.488 175 0.403 200 0.318 Determine the order of the reaction and the value of the rate constant. What is the rate of reaction when [A] = 0.10 M?

Problema 53a
This reaction was monitored as a function of time: A → B + C A plot of ln[A] versus time yields a straight line with slope -0.0045/s. a. What is the value of the rate constant (k) for this reaction at this temperature?
Problema 53b
This reaction was monitored as a function of time: A → B + C A plot of ln[A] versus time yields a straight line with slope -0.0045/s. b. Write the rate law for the reaction.
Problema 53c
This reaction was monitored as a function of time: A → B + C A plot of ln[A] versus time yields a straight line with slope -0.0045/s. c. What is the half-life?
Problema 53d
This reaction was monitored as a function of time: A → B + C A plot of ln[A] versus time yields a straight line with slope -0.0045/s. d. If the initial concentration of A is 0.250 M, what is the concentration after 225 s?
Problema 54a
This reaction was monitored as a function of time: AB → A + B A plot of 1/[AB] versus time yields a straight line with a slope of +0.55/Ms.
a. What is the value of the rate constant (k) for this reaction at this temperature?
Problema 54b
This reaction was monitored as a function of time: AB → A + B A plot of 1/[AB] versus time yields a straight line with a slope of +0.55/Ms. b. Write the rate law for the reaction.
Problema 54c
This reaction was monitored as a function of time: AB → A + B A plot of 1/[AB] versus time yields a straight line with a slope of +0.55/Ms. c. What is the half-life when the initial concentration is 0.55 M?
Problema 54d
This reaction was monitored as a function of time: AB → A + B A plot of 1/[AB] versus time yields a straight line with a slope of +0.55/Ms.
d. If the initial concentration of AB is 0.250 M, and the reaction mixture initially contains no products, what are the concentrations of A and B after 75 s?
- a. What is the half-life for the first-order decomposition of SO2Cl2 with a rate constant of 1.42 x 10^-4 s^-1? b. How long will it take for the concentration of SO2Cl2 to decrease to 25% of its initial concentration? c. If the initial concentration of SO2Cl2 is 1.00 M, how long will it take for the concentration to decrease to 0.78 M? d. If the initial concentration of SO2Cl2 is 0.150 M, what is the concentration of SO2Cl2 after 2.00 x 10^2 s? After 5.00 x 10^2 s?
Problema 55
- The decomposition of XY is second order in XY and has a rate constant of 7.02 * 10^-3 M^-1 s^-1 at a certain temperature. b. How long will it take for the concentration of XY to decrease to 12.5% of its initial concentration when the initial concentration is 0.100 M? When the initial concentration is 0.200 M? c. If the initial concentration of XY is 0.150 M, how long will it take for the concentration to decrease to 0.062 M? d. If the initial concentration of XY is 0.050 M, what is the concentration of XY after 5.0 * 10^1 s? After 5.50 * 10^2 s?
Problema 56
Ch.14 - Chemical Kinetics
