What reagents should be used to carry out the following syntheses?

What reagents should be used to carry out the following syntheses?

What reagents should be used to carry out the following syntheses?

What reagents should be used to carry out the following syntheses?

Draw the structures and give the common and systematic names for alkynes with molecular formula C₇H₁₂. Ignore stereosiomers. (Hint: There are 14.)

How many would there be if stereoisomers are included?

Draw the mechanism for the following reaction:

How can the following compounds be synthesized, starting with a hydrocarbon that has the same number of carbons as the desired product?

b. CH₃CH₂CH₂CH₂OH

How can the following compounds be synthesized, starting with a hydrocarbon that has the same number of carbons as the desired product?

c.

What reagents would you use for the following syntheses?

a. (Z)-3-hexene from 3-hexyne

What reagents would you use for the following syntheses?

b. (E)-3-hexene from 3-hexyne

What reagents would you use for the following syntheses?

c. hexane from 3-hexyne

What is the major product of the reaction of 1 mol of propyne with each of the following reagents?

c. Br₂ (1 mol)/CH₂Cl₂

What is the major product of the reaction of 1 mol of propyne with each of the following reagents?

d. Br₂ (2 mol)/CH₂Cl₂

What is the major product of the reaction of 1 mol of propyne with each of the following reagents?

e. aqueous H₂SO₄, HgSO₄

f. R₂BH in THF followed by H₂O₂/HO⁻ /H₂O

What is the major product of the reaction of 1 mol of propyne with each of the following reagents?

g. excess H₂, Pd/C

h. H₂/Lindlar catalyst

What is the major product of the reaction of 1 mol of propyne with each of the following reagents?

i. sodium amide

What is the major product of the reaction of 1 mol of propyne with each of the following reagents?

j. the product of part i followed by 1-chloropropane

Answer Problem 39, parts a–h, using 2-butyne as the starting material instead of propyne.

a. HBr (1 mol)

b. HBr (2 mol)

Answer Problem 39 , parts a–h, using 2-butyne as the starting material instead of propyne.

c. Br₂ (1 mol)/CH₂Cl₂

Answer Problem 39 , parts a–h, using 2-butyne as the starting material instead of propyne.

d. Br₂ (2 mol)/CH₂Cl₂

Answer Problem 39, parts a–h, using 2-butyne as the starting material instead of propyne.

e. aqueous H₂SO₄, HgSO₄

Answer Problem 39, parts a–h, using 2-butyne as the starting material instead of propyne.

f. R₂BH in THF followed by H₂O₂/HO⁻ /H₂O

Answer Problem 39, parts a–h, using 2-butyne as the starting material instead of propyne.

g. excess H₂, Pd/C

Answer Problem 39, parts a–h, using 2-butyne as the starting material instead of propyne.

h. H₂/Lindlar catalyst

What is each compound's systematic name?

a. CH₃C☰CCH₂CH₂CH₂CH═CH₂

What is each compound's systematic name?

b.

What is each compound's systematic name?

e.

f.

What is the molecular formula of a hydrocarbon that has 1 triple bond, 2 double bonds, 1 ring, and 32 carbons?

a. Starting with 3-methyl-1-butyne, how can you prepare the following alcohols?

  1. 2-methyl-2-butanol

b. In each case, a second alcohol would also be obtained. What alcohol would it be?