Predict the major products of the following reactions.

(a)

Predict the major products of the following reactions.

(b)

Predict the major products of the following reactions.

(c)

Predict the major products of the following reactions.

(d)

Predict the major products of the following reactions.

(e)

Predict the major products of the following reactions.

(f)

Predict the major products of the following reactions.

(g)

Predict the major products of the following reactions.

(h)

Predict the major products of the following reactions.

(i)

Predict the major products of the following reactions.

(j)

Rank the following carbonyl compounds in order of increasing equilibrium constant for hydration:

CH₃COCH₂Cl ClCH₂CHO CH₂O CH₃COCH₃ CH₃CHO

Acetals can serve as protecting groups for 1,2-diols, as well as for aldehydes and ketones. When the acetal is formed from acetone plus the diol, the acetal is called an acetonide. Show the acetonides formed from these diols with acetone under acid catalysis.

Acetals can serve as protecting groups for 1,2-diols, as well as for aldehydes and ketones. When the acetal is formed from acetone plus the diol, the acetal is called an acetonide. Show the acetonides formed from these diols with acetone under acid catalysis.

Acetals can serve as protecting groups for 1,2-diols, as well as for aldehydes and ketones. When the acetal is formed from acetone plus the diol, the acetal is called an acetonide. Show the acetonides formed from these diols with acetone under acid catalysis.

The following compounds undergo McLafferty rearrangement in the mass spectrometer. Predict the masses of the resulting charged fragments.

(b) 3-methylhexan-2-one

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(a)

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(b)

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(c)

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(d)

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(e)

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(f)

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(g)

Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.

(h)

For each compound,

1. name the functional group.

2. show what compound(s) result from complete hydrolysis.

(a)

For each compound,

1. name the functional group.

2. show what compound(s) result from complete hydrolysis.

(b)

For each compound,

1. name the functional group.

2. show what compound(s) result from complete hydrolysis.

(c)

For each compound,

1. name the functional group.

2. show what compound(s) result from complete hydrolysis.

(d)

For each compound,

1. name the functional group.

2. show what compound(s) result from complete hydrolysis.

(e)

For each compound,

1. name the functional group.

2. show what compound(s) result from complete hydrolysis.

(g)

For each compound,

1. name the functional group.

2. show what compound(s) result from complete hydrolysis.

(h)