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Alkene Reactivity: Controlled Hydration, Dihydroxylation, and Oxidative Cleavage

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Oxymercuration

  • Acid-catalyzed oxymercuration-reduction mechanism
    09:01
  • General properties of oxymercuration-reduction.
    05:

Hydroboration

  • General properties of hydroboration-oxidation.
    06:38
  • Acid-catalyzed hydroboration-oxidation mechanism
    06:14

Epoxidation

  • Halohydrins to epoxides via intramolecular SN2.
    02:26
  • General properties of epoxidation.
    02:19
  • The mechanism of how peroxy acids make epoxides.
    03:19

Epoxide Reactions

  • Base-Catalyzed Epoxide Ring-Opening
    04:44
  • Acid-Catalyzed Epoxide Ring-Opening
    04:34

Dihydroxylation

  • General properties of syn vicinal dihydroxylation.
    03:50
  • Predict the product for the following multi-step reaction.
    04:42

Ozonolysis

  • General properties of ozonolysis.
    06:30

Ozonolysis Full Mechanism

  • Predict the products and show the mechanism:
    12:11
  • General Mechanism:
    07:48
  • Reductive Workup Mechanism:
    03:16

Oxidative Cleavage

  • General properties of strong oxidative cleavage.
    06:00