Magnetic Properties of Complex Ions: Octahedral Complexes definitions Flashcards
Magnetic Properties of Complex Ions: Octahedral Complexes definitions
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Octahedral ComplexA coordination compound where a central metal atom is surrounded by six ligands in an octahedral geometry.LigandAn ion or molecule that binds to a central metal atom to form a coordination complex.Weak Field LigandA ligand that causes a small splitting of d orbitals, leading to high spin complexes.Strong Field LigandA ligand that causes a large splitting of d orbitals, leading to low spin complexes.DeltaThe energy difference between split d orbitals in a coordination complex.High Spin ComplexA complex where electrons occupy higher energy orbitals, often resulting in paramagnetism.Low Spin ComplexA complex where electrons pair in lower energy orbitals, potentially leading to diamagnetism.ParamagnetismA form of magnetism where unpaired electrons cause attraction to a magnetic field.DiamagnetismA form of magnetism where all electrons are paired, causing repulsion from a magnetic field.d OrbitalsThe set of five orbitals in the third energy level of an atom, important in transition metal chemistry.Degenerate OrbitalsOrbitals that have the same energy level in a given atom or ion.Energy CostThe energy required for an electron to move from a lower to a higher energy orbital.