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Bruice 8th EditionCh. 16 - Reactions of Aldehydes and Ketones • More Reactions of Carboxylic Acid Derivatives문제 65a
Identify A through O:
문제 65b
Identify A through O:
문제 65c
Identify A through O:
문제 65d
Identify A through O:
문제 65e
Identify A through O:
문제 65f
Identify A through O:
문제 65g
Identify A through O:
문제 65h
Identify A through O:
문제 66e,f
What are the products of the following reactions?
e.
f.
문제 66i
What are the products of the following reactions?
i.
문제 66j
What are the products of the following reactions?
j.
문제 67
The only organic compound obtained when compound Z undergoes the following sequence of reactions gives the 1H NMR spectrum shown. Identify compound Z.
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문제 68a
Propose a mechanism for each of the following reactions:
a.
문제 68b
Propose a mechanism for each of the following reactions:
b.
문제 69
How many signals would the product of the following reaction show in
a. its 1H NMR spectrum?
b. its 13C NMR spectrum?
문제 70
Fill in the boxes with the appropriate reagents:
문제 71
Rank the following compounds from most reactive to least reactive toward nucleophilic addition:
문제 72a
How could you convert N-methylbenzamide to the following compounds?
a. N-methylbenzylamine
문제 72b
How could you convert N-methylbenzamide to the following compounds?
b. benzoic acid
문제 72c
How could you convert N-methylbenzamide to the following compounds?
c. methyl benzoate
문제 72d
How could you convert N-methylbenzamide to the following compounds?
d. benzyl alcohol
문제 73c,d
What are the products of the following reactions? Show all stereoisomers that are formed.
c.
d.
문제 74a
List three different sets of reagents (each set consisting of a carbonyl compound and a Grignard reagent) that could be used to prepare each of the following tertiary alcohols:
a.
문제 74b
List three different sets of reagents (each set consisting of a carbonyl compound and a Grignard reagent) that could be used to prepare each of the following tertiary alcohols:
b.
문제 75a,b
What product is formed when 3-methyl-2-cyclohexenone reacts with each of the following reagents?
a. CH3MgBr followed by H3O+
b. (CH3CH2)2CuLi followed by H3O+
문제 75c,d
What product is formed when 3-methyl-2-cyclohexenone reacts with each of the following reagents?
c. HBr
d. CH3CH2SH
문제 77c,d
What is the product of each of the following reactions?
c.
d.
문제 78a
Propose a mechanism for each of the following reactions:
a.
문제 78b
Propose a mechanism for each of the following reactions:
b.
문제 79b
Draw structures for A-D for each of the following:
b.
